Catalysis, by organometallic

B. Comils, W. A. Herrmann, eAs., Applied Homogeneous Catalysis by Organometallic Compounds, VCH, Weinheim, 1996... 

Vacancies were later called coordinately unsaturated sites (cus). This is more in line with terminology used in organometallic chemistry. In view of the present understanding of the nature of the active sites, SBMS or Co(Ni)-Mo-S, the following discussion describes mechanisms in terms of catalysis by organometallic complexes. The references available on this topic are too numerous to mention, and the mechanisms are very well understood. A particularly useful reference is the book by Candlin, Taylor, and Thompson (90), although there are many others that can be consulted. 

The C-H transformation in the synthesis of fine chemicals can be separated in reactions employing catalysis by organometallic compounds and metal-free synthesis. Organometallic catalyzed functionalization is usually performed in liquid or gas/liquid reactions whereas the metal-free synthesis of fine chemicals often occurs as a gas-phase reaction. 

Soluble polymers have attracted recent attention in catalysis and combinatorial chemistry.1 3 When used in catalysis by organometallic compounds, soluble polymer ligands offer the following advantages The reaction is homogeneous in nature and separation of catalysts can be easily achieved by filtration or precipitation. We have now developed a new class of polymer ligands based on fluoroacrylate-arylphosphine copolymers for catalysis in periluorocarbon solvents and supercritical C02 (scC02). 

Reactions of Oiganoinetallic Complexes 686 Catalysis by Organometallic Compounds 705 Slereochenvcally Nmrigid Molecules 723 Conclusion 730... 

Carborane-metal complexes, 8, 87-113 Catalysis by organometallics carbonylation, 6, 158-163 hydroformylation, 6, 128-136 olefin reactions, 7, 199-202 organic syntheses by nickel compounds, 8, 48-83 reviews, 10, 331-336 Cationic metal carbonyls, 8, 117-159 Chromium carbonyls, 8, 133-159, see also Benchrotrenes Cobaloximes, 7, 161, 203 Cobalt carbonyl, 6, 119-163 8, 152-155 Cotton-Kraihanzel method, 10, 213-214 Coupling reactions, on nickel, 8, 30-39, 82-83... 

Blaser, H.-U., Indolese, A., Schnyder, A. Applied homogeneous catalysis by organometallic complexes. Curr. Sci. 2000, 78, 1336-1344. 

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