Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Carboxyl groups, formation from cellulose

Carbon monoxide, evolution from cellulose on beating, 428, 429 Carbonylation, of alkyl balides, 61 Carbonyl groups, formation from cellulose on heating, 426, 428, 435 Carboxyl groups, formation from cellulose on beating, 426, 427, 435 Cardenolides, synthesis of 1,2-cis-, 267 Cellobiose, /8-, mutarotation of, 23 Cellulase, 376 Cellulose... [Pg.501]

In an optimally controlled process free from transition-metal ions hydrogen peroxide bleaching is remarkably safe, there being no reported detrimental effects of bleaching at around 100 °C or for more than several hours [143]. Under such conditions, most of the peroxide appears to be consumed in the oxidation of chain end units of the cellulose macromolecule. The other major effect on the substrate is oxidation of secondary hydroxy to keto groups, accompanied by the formation of very few aldehyde or carboxyl groups [235]. [Pg.121]

The main causes for the formation of carbonyl and carboxyl groups in cellulose are isolation and purification procedures besides natural aging. This applies in particular to cellulosic pulps from wood, which has undergone a number of processing steps to be freed from lignin, hemicelluloses, and extractives. [Pg.3]

Heat catalyzes free radical formation in cellulose. Aldehydes form from C2 and C3 hydroxyls. Aldehydes oxidize to carboxyls, and with dehydration, carbon monoxide (CO) and carbon dioxide (C02) form as well as conjugated carbonyl-ethylenic chromophoric groups that selectively absorb blue light and impart yellowness (35). During the induction stage of cellulose oxidation, yellowness may increase steadily with selective carbonyl and ethylene group formation. By artificially aging... [Pg.75]

Schemes are available, however, that start from the free carboxylic acid, plus an activator . Dicyclohexylcarbodiimide, DCC, has been extensively employed as a promoter in esterification reactions, and in protein chemistry for peptide bond formation [187]. Although the reagent is toxic, and a stoichiometric concentration or more is necessary, this procedure is very useful, especially when a new derivative is targeted. The reaction usually proceeds at room temperature, is not subject to steric hindrance, and the conditions are mild, so that several types of functional groups can be employed, including acid-sensitive unsaturated acyl groups. In combination with 4-pyrrolidinonepyridine, this reagent has been employed for the preparation of long-chain fatty esters of cellulose from carboxylic acids, as depicted in Fig. 5 [166,185,188] ... Schemes are available, however, that start from the free carboxylic acid, plus an activator . Dicyclohexylcarbodiimide, DCC, has been extensively employed as a promoter in esterification reactions, and in protein chemistry for peptide bond formation [187]. Although the reagent is toxic, and a stoichiometric concentration or more is necessary, this procedure is very useful, especially when a new derivative is targeted. The reaction usually proceeds at room temperature, is not subject to steric hindrance, and the conditions are mild, so that several types of functional groups can be employed, including acid-sensitive unsaturated acyl groups. In combination with 4-pyrrolidinonepyridine, this reagent has been employed for the preparation of long-chain fatty esters of cellulose from carboxylic acids, as depicted in Fig. 5 [166,185,188] ...

See other pages where Carboxyl groups, formation from cellulose is mentioned: [Pg.299]    [Pg.86]    [Pg.197]    [Pg.7]    [Pg.15]    [Pg.23]    [Pg.239]    [Pg.247]    [Pg.28]    [Pg.128]    [Pg.341]    [Pg.33]    [Pg.436]    [Pg.312]    [Pg.280]    [Pg.176]    [Pg.52]    [Pg.296]    [Pg.114]    [Pg.19]    [Pg.325]    [Pg.321]    [Pg.139]    [Pg.700]    [Pg.30]    [Pg.301]    [Pg.1956]    [Pg.52]    [Pg.173]    [Pg.315]    [Pg.29]    [Pg.173]    [Pg.206]    [Pg.341]    [Pg.58]    [Pg.17]    [Pg.125]    [Pg.61]    [Pg.60]    [Pg.607]    [Pg.392]    [Pg.513]    [Pg.127]    [Pg.503]    [Pg.125]   


SEARCH



Carboxyl Cellulose

Carboxyl Cellulosic

Carboxyl groups formation

Carboxylate formation

Carboxylates formation

Formation from carboxyl

Formation from carboxyl group

Groups from

© 2024 chempedia.info