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Carbonyl compounds carbon-centred radicals

Oxidation is facilitated by a neighbouring carbonyl group which stabilises the initially formed carbon-centred carbohydrate radical. The experimental order of reactivity was acetoin>hydro acetone>>D-gluconic acid > standard ketohexoses>> standard aldopentoses>standard aldohexoses>D-glucitol D-fructose and L-sorbose gave dicarbonyl compounds as the primary products and aldopentoses furnished aldotetroses. ... [Pg.12]

See other pages where Carbonyl compounds carbon-centred radicals is mentioned: [Pg.1046]    [Pg.219]    [Pg.1046]    [Pg.270]    [Pg.997]    [Pg.20]    [Pg.93]    [Pg.219]    [Pg.5]    [Pg.98]    [Pg.209]    [Pg.276]    [Pg.109]    [Pg.41]   
See also in sourсe #XX -- [ Pg.765 ]



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Carbon centres

Carbon radicals

Carbon-centred

Carbon-centred radicals

Carbonate radical

Carbonyl carbon

Carbonyl carbonate

Carbonyl compounds 3-carbon

Carbonylation radical

Centres radical

Radical carbonylations

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