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Carbon versus oxygen alkylation

Carbon Versus Oxygen Alkylation and Enolate Reactivity... [Pg.702]

In the first reaction (Table 8.6, item 23), alkylation of the anion of cyclohexanone is not reversible. Hence, the question of O-alkylation (Equation 8.35) versus C-alkylation (Equation 8.36) is a kinetic problem (AH° < 0 for both O- and C-alkylation, Table 1.1) and, in principle, the enolate anion of cyclohexanone could alkylate on carbon and/or oxygen. [Pg.661]

SECTION 1.7. OXYGEN VERSUS CARBON AS THE SITE OF ALKYLATION... [Pg.23]

Table 5-22. Oxygen versus carbon alkylation in the reaction of two sodium are-nolates with haloalkanes at room temperature [370, 371],... Table 5-22. Oxygen versus carbon alkylation in the reaction of two sodium are-nolates with haloalkanes at room temperature [370, 371],...
Miscellaneous Reactions.- Oxygen versus carbon alkylation of p-... [Pg.334]

Breslow, R., Groves, K. and Mayer, M.U., Antihydrophobic cosolvent effects for alkylation reactions in water solution, particularly oxygen versus carbon alkylations of phenoxide ions, /. Am. Chem. Soc., 2002, 124,... [Pg.28]

See other pages where Carbon versus oxygen alkylation is mentioned: [Pg.456]    [Pg.366]    [Pg.834]    [Pg.109]    [Pg.23]    [Pg.27]    [Pg.389]    [Pg.629]    [Pg.503]    [Pg.157]    [Pg.188]    [Pg.924]    [Pg.154]    [Pg.16]    [Pg.102]    [Pg.804]    [Pg.23]    [Pg.70]    [Pg.22]    [Pg.23]    [Pg.381]   
See also in sourсe #XX -- [ Pg.4 , Pg.367 ]



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Alkyl carbonate

Alkylation carbon

Alkylation oxygen

Carbon oxygenated

Carbon oxygenation

Oxygen versus Carbon as the Site of Alkylation

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