Carbon-supported transition-metal

Van der Putten, A., A. Elzing, W. Visscher, E. Barendrecht (1986). Oxygen reduction on pyrolyzed carbon supported transition metal chelates. J. Electroanal. Chem. 205, 233-244. 

Van Veen JAR, Van Baar JF, Kroese KJ (1981) Effect of heat treatment on the performance of carbon-supported transition metal chelates in the electrochemical reduction of oxygen. J Chem Soc Faraday Trans l(77) 2827-2843... 

Figure 5.27. Thiophene HDS activity for the different carbon-supported transition-metal sulfides under standard conditions (3.33 kPa thiophene, 1 kPa H2S, and T = 573 K). Adapted from E.J.M. Hensenl l.

Very recently a critical review of the work on heat-treated macrocylic complexes on carbon was published It showed that the results for gas diffusion electrodes obtained can hardly be compared with each other. The activity and pyrolysis behaviour of carbon-supported transition metal chelates is determined by various factors such as the chelate, the texture of the carbon, the dispersion of the catalyst on the support, the kinetics of the pyrolysis reactions, etc. The processes which occur during the metal loading on the carbon and the pyrolysis were discussed. The authors developed a new carbon modified rotating ring disc electrode which can be used for quick comparisons of both the activity and selectivity of carbon-supported catalysts... 

Shu Y, Oyama ST (2005) Synthesis, characterization, and hydrotreating activity of carbon-supported transition metal phosphides. Carbon 43 1517-1532... 

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