Carbon magnetic properties

Tungsten pentachlofide [13470-13-8], WCl, mp 243°C, bp 275.6°C, is a black, crystalline, deHquescent soHd. It is only slightly soluble in carbon disulfide and decomposes in water to the blue oxide, 200 2. Magnetic properties suggest that tungsten pentachlofide may contain trinuclear clusters in the soHd state, but this stmcture has not been defined. Tungsten pentachlofide may be prepared by the reduction of the hexachloride with red phosphoms (9). 

Magnetic properties of iron nanocrystals nested in carbon cages, which grew on the cathode deposit, have been studied by Fliura el al.[29]. Magnetization (M-H) curves showed that the coercive force. He, of... 

Majetich and coworkers have studied magnetic properties of carbon-coated Co[32], Gd2C3, and FIo2C3 nanocrystals[33] formed in the chamber soot. A brief account on the coated Co nanocrystals is given here. They extracted magnetic nanocrystals from the crude soot with a magnetic gradient field technique. 

The surface properties of these nano-objects match those of metal nano crystals prepared in ultrahigh vacuum, for example the C - O stretch of adsorbed carbon monoxide or the magnetic properties of cobalt particles embedded in PVP. This demonstrates the clean character of the surface of these particles and its availabihty for reactivity studies. 

Large platinum carbonyl clusters have been investigated as models for the adsorption of carbon monoxide on platinum surfaces and on platinum electrodes. An issue is how large the clusters must be before they adopt the properties of the bulk metal. Teo et al. have investigated the magnetic properties of the clusters [Pt6(CO)12]2+, [Pt9(CO)18]2+, [Pt y(CO)22f+, and... 

Studies on di- and trinuclear metal complexes bridged by carbonate or hydrogencarbonate are mainly noted from three areas (i) fixation and activation of C02 from the viewpoint of environmental protection 462 164 (ii) functional models for zinc-containing carbonic anhydrase (Volume 8) and (iii) the relationship between the bridging modes of carbonate and magnetic properties. 

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