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Carbon hydrogen bonds bond dissociation energies

Figure 8. 5is-allylic carbon-hydrogen bond. The dissociation energy of this bond is lower than allylic and alky] carbon-hydrogen bonds, and therefore the iiy-allylic bond is favored for attack by LOO which explains the susceptibility of polyunsaturated lipids. [Pg.111]

Thermal Properties. Thermodynamic stabiUty of the chemical bonds comprising the PPS backbone is quite high. The bond dissociation energies (at 25°C) for the carbon—carbon, carbon—hydrogen, and carbon—sulfur bonds found in PPS are as follows C—C, 477 kj/mol (114 kcal/mol) ... [Pg.445]

Resonance theory can also account for the stability of the allyl radical. For example, to form an ethylene radical from ethylene requites a bond dissociation energy of 410 kj/mol (98 kcal/mol), whereas the bond dissociation energy to form an allyl radical from propylene requites 368 kj/mol (88 kcal/mol). This difference results entirely from resonance stabilization. The electron spin resonance spectmm of the allyl radical shows three, not four, types of hydrogen signals. The infrared spectmm shows one type, not two, of carbon—carbon bonds. These data imply the existence, at least on the time scale probed, of a symmetric molecule. The two equivalent resonance stmctures for the allyl radical are as follows ... [Pg.124]

The last example represents a fairly rare elimination of hydrogen fluoride in preference to hydrogen chloride, a reaction that deserves a more detailed discussion A comparison of bond dissociation energies of carbon-halogen bonds shows that the carbon-fluorine bond is much stronger than the carbon-chlorine, carbon-bromine, and carbon-iodme bonds 108-116, 83 5, 70, and 56 kcal/mol, respec-... [Pg.894]

Caibon has eight electrons in its valence shell in both methane and carbon tetrafluoride. By forming covalent bonds to four other atoms, carbon achieves a stable electron configuration analogous to neon. Each covalent bond in methane and carbon tetrafluoride is quite strong—comparable to the bond between hydrogens in Fl2 in bond dissociation energy. [Pg.13]

A very useful thermodynamic cycle links three important physical properties homolytic bond dissociation energies (BDE), electron affinities (EA), and acidities. It has been used in the gas phase and solution to determine, sometimes with high accuracy, carbon acidities (Scheme 3.6). " For example, the BDE of methane has been established as 104.9 0.1 kcahmol " " and the EA of the methyl radical, 1.8 0.7 kcal/mol, has been determined with high accuracy by photoelectron spectroscopy (PES) on the methyl anion (i.e., electron binding energy measurements). Of course, the ionization potential of the hydrogen atom is well established, 313.6 kcal/ mol, and as a result, a gas-phase acidity (A//acid) of 416.7 0.7 kcal/mol has been... [Pg.96]

Similarly, if we look at the H-C bond-dissociation energies of the hydrocarbons shown in Table 4-6, we would infer that Cl- would remove a hydrogen most rapidly from the carbon forming the weakest C-H bond and, again, this is very much in accord with experience. For example, the chlorination of methylbenzene (toluene) in sunlight leads to the substitution of a methyl hydro-... [Pg.96]

Carbon-hydrogen bonds, such as those in hydrocarbons like methane and ethane, have dissociation energies close to 400 kj-mol whereas single bonds between carbon and fluorine have dissociation energies close to 500 kj-mol-1. The greater strength of a carbon-fluorine bond helps to explain why fluorocarbon polymers are very resistant to chemical attack. They are used to construct valves for corrosive gases and to line the interiors of chemical reactors. [Pg.229]


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See also in sourсe #XX -- [ Pg.123 , Pg.124 ]




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Bond dissociation energies carbon-hydrogen radicals

Bond dissociation energy

Bond dissociation energy values carbon-hydrogen

Bonds bond dissociation energies

Carbon Hydrogen Bond Dissociation

Carbon bond dissociation energies

Carbon dissociating

Carbon dissociation

Carbon dissociative

Carbon hydrogen bonds dissociation energies

Carbon-hydrogen bond energy

Carbon-hydrogen bonds

Dissociation carbonate

Dissociation hydrogen bonds

Dissociative bond energy

Hydrogen bond dissociation energies

Hydrogen bond energy

Hydrogen bonding bond energies

Hydrogen bonding energies

Hydrogen dissociation

Hydrogen dissociation energy

Hydrogen energy

Hydrogenation energies

Hydrogenative dissociation

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