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Carbon-Halogen Bond Formation with Group 8 Metals

Carbon-Halogen Bond Formation with Group 11 Metals... [Pg.21]

In a general sense, the Reformatsky reaction can be taken as subsuming all enolate formations by oxidative addition of a metal or a low-valent metal salt into a carbon-halogen bond activated by a vicinal carbonyl group, followed by reaction of the enolates thus formed with an appropriate electrophile (Scheme 14.1).1-3 The insertion of metallic zinc into a-haloesters is the historically first and still most widely used form of this process,4 to which this chapter is confined. It is the mode of enolate formation that distinguishes the Reformatsky reaction from other fields of metal enolate chemistry. [Pg.287]


See other pages where Carbon-Halogen Bond Formation with Group 8 Metals is mentioned: [Pg.84]    [Pg.156]    [Pg.452]    [Pg.53]    [Pg.29]    [Pg.245]    [Pg.5345]    [Pg.152]    [Pg.67]    [Pg.386]    [Pg.207]    [Pg.209]    [Pg.156]    [Pg.194]    [Pg.5344]    [Pg.386]    [Pg.1]    [Pg.847]    [Pg.156]    [Pg.430]    [Pg.432]    [Pg.10]    [Pg.347]    [Pg.48]    [Pg.90]    [Pg.182]    [Pg.102]    [Pg.241]    [Pg.4882]    [Pg.330]    [Pg.182]    [Pg.31]    [Pg.83]    [Pg.718]    [Pg.90]    [Pg.4881]    [Pg.119]    [Pg.485]    [Pg.53]    [Pg.279]    [Pg.612]   


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Bond , 16-25 with carbon

Bonding carbon-metal bond

Bonds carbon metal

Bonds carbon-halogen bond

Bonds carbon-metal bond

Carbon Group

Carbon halogenation

Carbon-halogen bond formation

Carbon-halogen bonds

Carbon-halogen, Group 8/9 metals

Carbon-metal bond formation

Formates, metalated

Halogen bonding

Halogen bonds/bonding

Halogen groups

Halogens with metals

Metal formate

Metal-halogen

Metal-halogen bonds

Metals, formation

With Halogens

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