Carbon dioxide can ignite a flammable mixture

In 1966, a naphtha tanker, the Alva Cape, was involved in a collision near New York and was severely damaged. Some naphtha was spilled, and the rest was pumped out into another vessel. The owners wanted to move the ship to a shipyard where it could be gas-freed and the damage could be surveyed, but the New York Fire Department said that the ship s tanks should be inerted before it was moved. The salvage company, therefore, ordered some carbon dioxide cylinders and hoses. Two tanks were inerted without incident, but when carbon dioxide was discharged into a third tank, an explosion occurred, followed by a fire. Four men were killed, and further explosions occurred in other tanks when they were heated by the fire. 

A similar incident occurred in France a year or two later. Carbon dioxide was injected into a tank containing jet fuel during a tryout of a firefighting system. The tank exploded, killing 18 people who were standing on the top. 

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