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Cage- macrocycles

Keywords Templates Hydrogen Bonding Self-assembly Cages Macrocycles Catenanes ... [Pg.91]

Mixed-valent silver(I,II) compounds containing Ag2<22 To investigate the effect of coexisting metal ions on the assembly of polyhedral silver cages, macrocyclic (V-donor ligand 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (tmc) has been used for in situ generation... [Pg.790]

Lariat ethers crown ethers with pendant chains Sepulchrates bicyclic caged macrocycles Spherands macrocycles with phenyl backbones... [Pg.2418]

Sepulchrates (7) are polyaza cage macrocycles. They are noted for their exceptionally strong hold on encapsulated metal... [Pg.2419]

Sepulchrates (7) are the most noted of the caged macrocyclic ligands and are the nitrogen analogs of the cryptands. The Co-N distances are 1.99 A for Co and 2.16 A for Co from crystallographic data, and do not vary greatly from other cobalt amines. ... [Pg.2430]

Structure and Bonding in Boron-Containing Macrocycles and Cages... [Pg.9]

Fig. 27. In vanadium borate 106 the macrocyclic borate ring (left) is sandwiched by two smaller (VO)60i2 rings (right) of triangular form via six axial B-( 3-0)-V bonds to form a cage-like cluster anion... Fig. 27. In vanadium borate 106 the macrocyclic borate ring (left) is sandwiched by two smaller (VO)60i2 rings (right) of triangular form via six axial B-( 3-0)-V bonds to form a cage-like cluster anion...
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Linked Macrocyclic and Cage Assemblies

Macrocycle cage system

The cage macrocycles

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