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Buchner method of ring expansion

Reaction of benzene with diazoacetic esters to give cyclohepta-2,4,6-trienecarboxylic acid esters. Cf. Pfau-Platter azulene synthesis. [Pg.96]

Direct Pd-catalyzed C-N and C-O bond formation from aryl halides and amines in the presence of stoichiometric amount of base. [Pg.98]

The C-O bond formation reaction follows a similar mechanistic pathway. [Pg.98]

Hartwig, J. F. J. Am. Chem. Soc. 1994, 116, 5969. John Flartwig earned his Ph.D. under Bergman and Anderson. He has moved from Yale University to the University of Illinois at Urbana-Champaign in 2006. Hartwig and Buchwald independently discovered this chemistry. [Pg.99]

GooBen, L. J. Paetzold, J. Brief O. Rivas-Nass, A. Karch, R. Kayser, B. Synlett 2005, 275. [Pg.99]

Buchner method of ring expansion Thermal or photochemical reaction of ethyl diazoacetate with benzenes and its homologs to give the isomeric esters of cycloheptatriene carboxylic acid. 68... [Pg.512]

Related reactions Buchner method of ring expansion ... [Pg.559]

See other pages where Buchner method of ring expansion is mentioned: [Pg.96]    [Pg.68]    [Pg.69]    [Pg.59]    [Pg.55]    [Pg.96]    [Pg.68]    [Pg.69]    [Pg.59]    [Pg.55]   
See also in sourсe #XX -- [ Pg.96 ]

See also in sourсe #XX -- [ Pg.59 ]

See also in sourсe #XX -- [ Pg.55 ]



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