Bubble elimination

Polymers can be classified according to the techniques used during the polymerization of the monomer. In bulk polymerization, only the monomer (and possibly eatalyst and initiator, but no solvent) is fed into the reactor. The monomer undergoes polymerization, at the end of whieh a (nearly) solid mass is removed as the polymer product. As we shall see later, bulk polymerization is employed widely in the manufacture of condensation polymers, where reactions are only mildly exothermic and viscosity is mostly low thus enhancing ready mixing, heat transfer, and bubble elimination. Solution polymerization involves polymerization of a monomer in a solvent in which both the monomer (reactant) and polymer (product) are soluble. Suspension polymerization refers to polymerization in an aqueous medium with the monomer as the dispersed phase. Consequently, the polymer resulting from such a system forms a solid dispersed phase. Emulsion polymerization is similar to suspension polymerization but the initiator is located in... 

The basic phenomenon involved is that particles of ore are carried upward and held in the froth by virtue of their being attached to an air bubble, as illustrated in the inset to Fig. XIII-4. Consider, for example, the gravity-free situation indicated in Fig. XIII-5 for the case of a spherical particle. The particle may be entirely in phase A or entirely in phase B. Alternatively, it may be located in the interface, in which case both 7sa nnd 7sb contribute to the total surface free energy of the system. Also, however, some liquid-liquid interface has been eliminated. It may be shown (see Problem XIII-12) that if there is a finite contact angle, 0sab> the stable position of the particle is at the interface, as shown in Fig. XIII-5Z>. Actual measured detachment forces are in the range of 5 to 20 dyn [60]. 

Bubble columns in series have been used to establish the same effective mix of plug-flow and back-mixing behavior required for Hquid-phase oxidation of cyclohexane, as obtained with staged reactors in series. WeU-mixed behavior has been established with both Hquid and air recycle. The choice of one bubble column reactor was motivated by the need to minimize sticky by-products that accumulated on the walls (93). Here, high air rate also increased conversion by eliminating reaction water from the reactor, thus illustrating that the choice of a reactor system need not always be based on compromise, and solutions to production and maintenance problems are complementary. Unlike the Hquid in most bubble columns, Hquid in this reactor was intentionally weU mixed. 

Compute a new set of values of tear variables by computing, one at a time, the bubble-point temperature at each stage based on the specified stage pressure and corresponding normalized values. The equation used is obtained by combining Eqs. (13-69) and (13-70) to eliminate yj j to give... 

Entrainment of fine particulate matter such as sand and silt in cooling water can contribute significantly to erosion-corrosion. In these cases it is important to eliminate or reduce the amount of particulate by settling or filtration. It may also be necessary to reduce or eliminate entrained gas bubbles. 

The evolution of gases, such as in dre example given above of dre formation of CO(g) in dre U airsfer of sulphur between carbon-saturated iron and a silicate slag, requires dre nucleation of bubbles before dre gas can be eliminated from the melt. The possibility of homogeneous nucleation seems unlikely, and the more probable source of gas bubbles would either be at the container ceramic walls, or on detached solid particles of the containing material which are... 

Flow surges in the seal drum are likely generated by the cyclic formation of large bubbles as the flare gas is discharged into the drum. These pulsations can be virtually eliminated by the use of a horizontal sparger ineorporating many small diameter holes arranged specifically to allow the open area to increase as flow increases. These holes must be spaced sufficiently far apart to avoid interference between bubbles. 

Air pockets or bubbles are left on the surface of all concrete. Good vibration and placing techniques will reduce their number but not eliminate them. Many air pockets have a small opening on the surface in relation to their size. Paints will not penetrate into such holes, with the result that air or solvent is trapped and subsequent expansion will cause the coating to blister. In addition, some air pockets are covered with a thin layer of cement that also has no strength and will cause loss of adhesion. 

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