Bright red

Dissolves in alkaline solutions to give purple-red solutions which are precipitated as lakes by heavy metal salts. Occurs naturally as a glucoside in madder but produced synthetically by fusing anthraquinone-2-sulphonic acid with NaOH and some KCIO3. Applied to the mordanted fibre. Al(OH)3 gives a bright red lake, Cr(OH)3 a red lake, FefOH) ... 

It is the simplest compound containing the -N = N- chromophore, but is of no practical importance since it lacks affinity for fibres. Normally it exists in the most stable trans form, but may be converted to a less stable, bright red as form, m.p. 71 -S C by ultra-violet irradiation. Cis to irans isomerization occurs rapidly on heating. 

KaOH solution in excess a bright red coloration is developed. 

Phthalein reaction. Fuse together carefully in a dry test-tube a few crystals of phthalic acid or of a phthalate and an equal quantity of ph tol moistened with 2 drops of cone. H2SO4. Cool, dissolve in water and add NaOH solution in excess the bright red colour of phenolphthalein in alkaline solution is produced. 

Formation of methyl-orange cf. p. 214). Dissolve about 0 3 g. of sul-phanilic acid in 2 ml. of 10% aqueous NajCOj solution. Cool m ice-water and add 2 to 3 drops of 20% NaNOj solution. Now add about I ml. of cold dil. HCl, shake and leave for 2-3 minutes. Meanwhile dissolve i drop of dimethylaniline in a few drops of dil. HCl, cool thoroughly in ice-water and then add to the cold diazo solution. Shake well and make alkaline with aqueous NaOH solution note the formation of a deep orange-yellow coloration or precipitate. On the addition of HCl, a bright red coloration is produced. 

The contents of B, which act as a control, are treated with mercuric chloride in order to inhibit the action of the enzyme, and then 10 ml. of urease solution are added. The solution is diluted with water and ammonium chloride added (in order to balance the ammonium chloride subsequently formed in A). Meth) l-red is then added and the solution is titrated with Mj 10 HCl from a second burette B until a bright red colour is obtained. 

Alnminon (qualitative test for aluminum). The reagent consists of 0.1% solution of the ammonium salt of aurin tricarboxylic acid. A bright red precipitate, persisting in alkaline solution, indicates aluminum. 

The color of red meat depends on oxygen. The color of the meat pigment myoglobin is purple. The bright red color of the fresh-as-cut meat is from oxymyoglobin. To preserve red meat, the objectives are to retard spoilage and weight loss, and to deUver red color at the consumer level. 

Cuprous iodomercurate [13876-85-2] Cu2Hgl4, is a bright red water-insoluble compound prepared by precipitation from a solution of K Hgl with cuprous chloride. It is used in temperature-indicating paints because it reversibly changes color to brown at 70°C (see Chromogenic materials). 

Reaction with nitrous acid can be used to differentiate primary, secondary, and tertiary mononitroparaffins. Primary nitroparaffins give nitrolic acids, which dissolve in alkali to form bright red salts. 

C to a bright red vapor. The soHd is stable when pure. It disproportionates in organic solvents and is decomposed by acids and alkaHes. It is hydrolyzed to H2Te02, Te, and HCl, and decomposed by HCl to Te and H2TeClg [17112-43-5]. Air oxidizes teUurium dichloride to Te02 and HCl. 

Tungsten hexafluoride dissolves in ben2ene or cyclohexane to give a bright red color, in dioxane a pale red, and in ether a violet-brown. 

Paprika and its oleoresin are approved for use in foods in general where its appHcation as a color additive frequendy ovedaps its use as a spice. Both products have good tinctorial strength and are used at 0.2—100 ppm to produce orange to bright red shades. 

Anthraquinone Dyes. Simple anthraquiaone dyes are used mainly to obtain bright reds, pinks, blues, greenish blues, turquoises, and bluish greens. They give a purer and brighter shade than found with most commonly available a2o dyes (see Dyes, anthraquinone). 

Carmine [1390-65-4] is the trade name for the aluminum lake of the red anthraquinone dye carminic acid obtained from the cochineal bug. The dye is obtained from the powdery form of cochineal by extraction with hot water, the extracts treated with aluminum salts, and the dye precipitated from the solution by the addition of ethanol. This water-soluble bright red dye is used for coloring shrimp, pork sausages, pharmaceuticals, and cosmetics. It is the only animal-derived dye approved as a colorant for foods and other products. 

Nickel (II) phthalocyanine [14055-02-8] M 571,3, m >300 , Wash well with H2O and boiling EtOH and sublime at high vacuum in a slight stream of C02. A special apparatus is used (see reference) with the phthallocyanine being heated to red heat. The sublimate is made of needles with an extremely bright red lustre. The powder is dull greenish blue in colour. [J Chem Soc 1719 7936.]... 

Demonstrations Take a strip — 0.25 mm X 1 cm X 15 cm of cold-rolled (work-hardened) brass and bend it (on edge) on the overhead until permanent deformation takes place. Anneal brass strip at bright red head for — 0.5 min to soften it. After cooling replace on overhead and show that permanent deformation takes place at a much smaller deflection than before. This illustrates the importance of large Uy in springs. 

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