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Bridging iodine

Keywords PMO, BTEB, Phenylene-Bridged, Iodine, UV-Visible. [Pg.233]

As previously described, the bridging iodine atom is located at the midpoint between two diplatinum units. (Adapted from Mitsumi et ah, 2001)... [Pg.629]

Its X-ray structure indicates the formation of a contact ion-pair where the complexed cation [K-18-crown-6 ] , shaped as "an overturned umbrella", is connected to the anion through three bridging iodine atoms. This arrangement allows the potassium ion to interact with other possible ligands in a direction perpendicular to the plane containing the crown-ether. [Pg.221]

Two typical layer structures, that of ehromium(III) chloride and that of mercury(II) iodide, are shown in Figure 12-5. In Hgl2, each mercury atom is surrounded by four iodine atoms at the corners of a tetrahedron each of these is a bridge iodine. In chromic chloride, each chromium ion is at the center of an octahedron of chloride ions again, each chloride is a... [Pg.188]

Shslis", [SbL ]x, [Sb2l lx)." Abinuclear Sb(III) complex with bridging iodine and sulfur atoms of the type LSb(/u.-I)2(/n-S)SbL is formed by reacting antimony powder with diiodine and (SPPh2NHPPh2S) (HL). ... [Pg.216]

Li[ Ybl2 C5(CH05 2] 2Et20 (lithium is surrounded by two oxygens and two bridging iodines, as above)... [Pg.437]

The crystal structure of [(CO)4MoI]2 has shown it to consist of two dimeric molecules formed by two octahedra sharing a common edge with bridging iodine atoms. ... [Pg.145]

The reaction between Bils and triphenylarsine oxide gave a complex, dinuclear product Bi2l6(Ph3AsO)3, in which each bismuth atom was in approximately octahedral co-ordination/ The first atom is attached to three terminal and three bridging iodine atoms (mean values 2.93 and 3.32 A), while the second is associated with the three bridging iodines and three oxygen atoms. [Pg.233]

Figure 12. Pr / Ru Left - a side view of one chain of condensed dusters with edge-bridging iodine. Line widths approximate bond populations. Right - a projection down the chains with the interchain bridging. Pr is shaded, Ru is crossed and iodine is open ellipsoids. Figure 12. Pr / Ru Left - a side view of one chain of condensed dusters with edge-bridging iodine. Line widths approximate bond populations. Right - a projection down the chains with the interchain bridging. Pr is shaded, Ru is crossed and iodine is open ellipsoids.

See other pages where Bridging iodine is mentioned: [Pg.66]    [Pg.839]    [Pg.312]    [Pg.314]    [Pg.320]    [Pg.326]    [Pg.329]    [Pg.677]    [Pg.305]    [Pg.108]    [Pg.302]    [Pg.302]    [Pg.169]    [Pg.245]    [Pg.166]    [Pg.752]    [Pg.437]    [Pg.333]    [Pg.333]    [Pg.511]    [Pg.534]    [Pg.770]    [Pg.397]    [Pg.941]    [Pg.215]    [Pg.751]    [Pg.2516]    [Pg.314]    [Pg.320]    [Pg.326]    [Pg.329]    [Pg.169]    [Pg.266]    [Pg.266]    [Pg.358]    [Pg.49]    [Pg.35]    [Pg.50]    [Pg.278]    [Pg.839]   
See also in sourсe #XX -- [ Pg.20 ]

See also in sourсe #XX -- [ Pg.20 ]




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