Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Bridged phosphine complexes molybdenum

The orange complex is air sensitive in the solid state. It is reasonably soluble and stable in THF but decomposes in nonpolar solvents, such as benzene, to give polymeric halogen-bridged products.9 It is paramagnetic with a magnetic moment of 3.63 BM, and its IR spectrum shows a very intense band at about 820 cm-1 due to coordinated THF. Its reactions with tertiary phosphines in THF give a series of molybdenum (III) tertiary phosphine complexes,9 and with trimethyl-silyl azide Mo(V) nitrido complexes are formed.8... [Pg.122]

When the molybdenum diethyldithiocarbamate (dete) complex 358 is treated with CS2 in the presence of PPh3, the phosphine serves to abstract sulfur from CS2. The resultant CS fragments are incorporated into two new bridging ligands of complex 359, One CS formally inserts onto an M—S... [Pg.69]

See other pages where Bridged phosphine complexes molybdenum is mentioned: [Pg.198]    [Pg.3373]    [Pg.253]    [Pg.3372]    [Pg.2140]    [Pg.182]    [Pg.188]    [Pg.30]    [Pg.93]    [Pg.145]    [Pg.977]    [Pg.1363]    [Pg.61]    [Pg.206]    [Pg.250]    [Pg.2]    [Pg.12]    [Pg.12]    [Pg.2816]    [Pg.3202]    [Pg.578]    [Pg.393]    [Pg.197]    [Pg.2]    [Pg.148]    [Pg.190]    [Pg.157]    [Pg.210]    [Pg.235]   
See also in sourсe #XX -- [ Pg.203 , Pg.209 , Pg.212 ]



SEARCH



Bridged phosphine complexes

Bridging phosphines

Molybdenum phosphine

© 2024 chempedia.info