Boron tribromide trifluoride

Bordetella pertussis Toxin Borer Sol Boroethane Boron Bromide Boron Chloride Boron Fluoride Boron Hydride Boron Tribromide Boron Trichloride Boron Trifluoride Botox... [Pg.636]

Aluminum phosphide Amyl trichlorosilane Benzoyl chloride Boron tribromide Boron trifluoride Boron trifluoride etherate Bromine pentafluoride Bromine trifluoride n-Butyl isocyanate Butyllithium Butyric anhydride Calcium Calcium carbide Chlorine trifluoride Chloro silanes Chlorosulfonic acid Chromium oxychloride Cyanamide Decaborane Diborane... [Pg.61]

Acrylic acid, Initiator, Water, 1148 Aluminium chloride, Water, 0062 Barium peroxide, Propane, 0216 1,3-Benzodithiolium perchlorate, 2677 1,1 -Bis(fluorooxy)tetrafluoroethane, 0641 Borane-tetrahydrofuran, 0138 Boron tribromide, Water, 0122 Bromine, Aluminium, Dichloromethane, 0261 Bromine, Tungsten, Tungsten trioxide, 0261 f 1,3-Butadiene, 1480 Calcium oxide, Water, 3937 Chlorine trifluoride, Refractory materials, 3981 Chromium trioxide, Acetic acid, 4242 Copper(II) oxide, Boron, 4281 Diazoacetonitrile, 0675 Dihydroxymaleic acid, 1447 Ethyl azide, 0872... [Pg.170]

Boron diiodophosphide, 0149 Boron tribromide, 0122 Boron trichloride, 0127 Boron trifluoride, 0129... [Pg.284]

Pentaborane Diborane Decaborane Sodium borate Boron trifluoride Calcium borate Boron tribromide Boron oxide Total dust Respirable fraction Sodium tetraborate Decahydrate... [Pg.1580]

The reaction is irreversible and can be used to synthesize aliphatic and aromatic esters. In addition, there are no complications involving water removal or azeotrope formation. Boron tribromide can be used in place of boron trichloride, but the bromide has a stronger tendency to halogenate the alkyl group of the alcohol (26). Boron trifluoride does not give the ester, but gives either a complex or dehydrated product. [Pg.215]

Borane-Sodium borohydride, 42 Borane-Tetrahydrofuran, 42 Boron tribromide, 43 Boron trichloride, 43 Boron trifluoride, 44 Boron trifluoride etherate, 3, 6, 10, 13, 43, 82, 99, 193, 200, 211, 306, 308, 321, 322... [Pg.406]

Borane carbonyl BHjCO Borazine B3N3H Boron tribromide BBr Boron trichloride BClj Boron trifluoride BF Bromodiborane BjHsBr Diborane(6) B2H... [Pg.151]

ESTERS Sodium benzeneselenolate. ETHERS Boron tribromide-Sodium iodide-15-Crown-5. Boron trifluoride etherate. Ferric chloride-Silica. Lithium iodide. Silicon(IV) chloride-Sodiuiu iodide. Sodium iodide-Pivaloyl chloride. 2,4,4,6-Tetrabromocyclohexadiene. Trichloro(methyl)silane. [Pg.309]

A comparison of catalytic activity of the triphenyl phosphate complexes of boron trifluoride,boron trichloride and boron tribromide showed that comparable rates of polymerization were obtained using the chloride or bromide complexes. The fluoride complex gave about half the rate of the bromide or chloride comparable molecular weights were obtained in all three cases. [Pg.316]

Boron trichloride, boron tribromide, and boron triiodide, in contrast to the trifluoride, are all rapidly hydrolyzed in water (explosively so in the case of BI3) to generate B(OH)3 and HX as indicated above, all are stronger Lewis acids than BF3. While BC13 and BBr3 are volatile liquids, BI3 is an unstable white solid that polymerizes on standing. The BX anions are all known, but the larger ones —especially BI4—require stabilization by a large cation. [Pg.166]

Boron Tribromide and Boron Triiodide. Boron tribromide is prepared commercially in relatively small quantities by the bromination of boron carbide, and its commercial use is limited. No commercial use for boron triiodide has been reported. Laboratory quantities of boron tribromide can be prepared by the reaction of aluminum bromide with boron trifluoride or a metal fluoroborate. Boron triiodide can be prepared in small quantities by the reaction of boron or a metal tetrahydroborate with iodine. [Pg.439]

Boron tribromide, 51 Boron trichloride. 51 Boron trifluoride, 50, 51, 113-115,... [Pg.240]

Boron tribromide Boron trichloride Boron trifluoride etherate Hydrocarbons, halogenated Hydrocarbons, halogenated Many solvents Strong, used to cleave ethers, acetals Strong, used to cleave ethers, acetals Moderate, very versatile... [Pg.280]

Boron is a Group HTA element that forms many covalent compounds by bonding to three other atoms. Typical examples include boron trifluoride, BF3 (mp — 127°C) boron trichloride, BCI3 (mp — 107°C) boron tribromide, BBr3 (mp -46°C) and boron triiodide, BI3 (mp 50°C). All are trigonal planar nonpolar molecules. [Pg.316]

Borabicyclo[3.3.1Jnonane (9-BBN), 31 Boric acid, 32 2-Bornene, 419 Boronobenzoic acid, 32 Boron oxide, 32 Boron tribromide, 33-34 Boron trichloride, 34-35 Boron triiluoride etherate, 7, 9, 35-36, 40, 124, 160, 161, 182, 229, 230, 430, 438 Boron trifluoride etherate—Acetic anhydride, 36-37... [Pg.260]

Ethers Acetyl p-toluenesulfonate. Boron tribromide. Boron trichloride. Boron trifluoride etherate—Acetic anhydride. Ferric chloride. Methylmagnesium iodide. Pyridine hydrochloride. Sodium borohydride. Sodium iodide. [Pg.513]

Rearrangement. Tertiary A -benzylglycinamides are subject to [l,2]-rearrangement by consecutive treatment with BBr3 and Et3N to afford phenylalaninamide analogues. The transformation cannot be effected by replacing boron tribromide with boron trifluoride. [Pg.79]