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Boiling Point of Linear Alkanes

In introducing the entropy of vaporization, we indicate that we intend to use Trou-ton s rule. A is the molar surface, which is related via the Avogadro Number NA to the surface of a single molecule. The gain of area is also dependent on the shape of [Pg.335]

Name Compound name n Number of carbon atoms [kJ mol ] Molar heat of [Pg.337]

What is the power law State about the molecule shape. [Pg.337]

Take care on the correct units. Try to explain the findings. There are further tests of interest Work out similarity theorems for other shapes of the molecules than spheres. Estimate whether the molecule radii obtained from the relation are in the correct range. Take notice that Lord Kelvin established such considerations [17,18]. [Pg.337]

According to Kelen and TUdds [37], an auxiliary variable is introduced [Pg.338]


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