Thermoplastic binders

Asbestos-reinforced organic binders (thermoplastics, duroplasts and elastomers) are widely utilized e.g. hardenable molding materials on the basis of asbestos-reinforced phenol or melamine resins for the manufacture of insulating components for combustion engines, components for electrical installations, cogwheels etc. Possible fiber substitutes are glass fibers, carbon fibers and other synthetic fibers (e.g. aramide fibers) and non-fiber fillers such as calcium carbonate, clay or talcum. 

Gun Propellents. Low sensitivity gun propeUants, often referred to as LOVA (low vulnerabUity ammunition), use RDX or HMX as the principal energy components, and desensitizing binders such as ceUulose acetate butyrate or thermoplastic elastomers (TPE) including poly acetal—polyurethane block copolymers, polystyrene—polyacrjiate copolymers, and glycidyl azide polymers (GAP) to provide the required mechanical... 

B. D. Nahloosky and G. A. Zimmerman, Thermoplastic Elastomers for S olid Propellant Binders, AERPL-TR-86-069, Aerojet Tactical Systems Co., Sacramento, Calif., Dec. 1986. 

The binder system of a plastic encapsulant consists of an epoxy resin, a hardener or curing agent, and an accelerating catalyst system. The conversion of epoxies from the Hquid (thermoplastic) state to tough, hard, thermoset soHds is accompHshed by the addition of chemically active compounds known as curing agents. Flame retardants (qv), usually in the form of halogens, are added to the epoxy resin backbone because epoxy resins are inherently flammable. 

AH forms and compositions of reinforcements, ie, mats, woven roving, glass, carbon, and aramid, are commonly used with these processes. Special continuous glass strand mats with a thermoplastic binder aHow preforms to be made using thermoforming techniques. These processes are used for tmck and autobody components, medical equipment cabinets, transportation seating, and other parts needed in the intermediate volume range (1,000—10,000 parts/yr). 

EthylceUulose [9004-57-3], a cellulose either (qv), as prepared commercially, ie, of high DS, is thermoplastic and has alow density (1.14 g/cm ). It forms films of good thermostabiUty and excellent flexibiUty and toughness. EthylceUulose is used in lacquers, inks, and adhesives and is combined with waxes and resins in the preparation of hot-melt plastics. It is also used as a pharmaceutical tablet binder. 

Examples of plasticizers include adsorbed water and ethylene glycol for vinyl binders, stearic acid and oleic acid for wax binders, glycerine and ethylene glycol for clay bodies, and molten oils and waxes for thermoplastic polymers used in injection mol ding. 

Soon after World War II the hard thermoplastic floor tile was developed. These tiles use coumarone resins as a binder for the other ingredients, which may contain fibrous fillers such as asbestos, inert fillers such as china clay and softeners such as paraffin wax. 

Binder, K., Non-Isothermal Long Term Creep (17 yrs.) Behavior of Thermoplastics Outdoors, Kunststoffe, No. 1988. 

Some specialized uses of PETN are summarized below. Expendable cartridges for small arms are made by coating unglazed grains or single base smokeless powder with PETN, spraying with plasticized thermoplastic binder and compression molding to the desired shape (Ref 99). Tucker et al (Ref 85) describe a spark detonator without primary expls. Secondary... 

Polystyrene. A thermoplastic used as a binder and fuel in expls and rocket propints. See Plastic fuels (Vol 3, C465-L) under Composite Propellants also Dinitropolystyrene in this Vol, N143-L to N144-R under Nitro Polymers and Propellants, Solid , also in this Vol... 

Polyvinylacetate. A thermoplastic primarily used as a binder in non-metallic cartridge cases (see Mil Spec below)... 

The quantity of conductive component varied from 15wt% to 30wt%. Solution of thermoplastic polymer in organic solvent was prepared separately. Then, a mixture of dry components Ni(OH)2 + graphite was added to that solution and mixed one more time. Content of polymer binder in composition of a dry electrode was 5-10wt%. 

Organic polymers and resins have also been used for zeolite binding. An early example is the use polyurethane in the formahon of vibration-resistant zeolite porous bodies for refrigerant drying [90]. Organic binders such as cellulose acetate and other cellulose-based polymers have also used to mitigate problems with binder dissolution in aqueous phase separations [91, 92]. Latex has also been used as a water-stable organic binder [93]. More recently, thermoplastic resins, such as polyethylene have also been used as binders for zeolites [94]. 

Chen, E.-T., Duo, Y.-Q., Luo, S.-G., Luo, Y.-J., and Tan, H.-M., Novel Segmented Thermoplastic Polyurethane Elastomers Based on Tetrahydrofuran/Ethylene Oxide Copolymers as High Energetic Propellant Binders, Propellants, Explosives, Pyrotechnics, Vol. 28, 2003, pp. 7. 

VAE, a copolymer of vinyl acetate with minor amounts of ethylene is used as an adhesive for paper, plastics and leather and as a binder for different paints. Shoes, tubes, toys and other articles of daily use also contain VAE polymers. The hydrolysis product of VAE polymers, EVOH, is a thermoplast and can therefore be processed by extrusion and injection moulding and is used as barrier polymer for O2 and CO2 (e.g. in packaging applications). 

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