Diagram binary, elements

Figure 17.21 The two basic binary diagram elements. In the phase transition loop (left diagram) solution 1 and solution 2 can be solid and solid, solid and liquid, or liquid and vapor, respectively. and are melting temperatures, boiling temperatures, or polymorphic phase transition temperatures for pure A and B respectively. Three representative tie-lines are shown. In the solvus (right diagram), solution 1 and solution 2 can be two solids or two liquids. Two representative tie-lines are shown.

The change of halide ion results in weaker acidic properties for LnCl3 as compared with LnF3. This means that equilibrium (1.1.41) with the participation of alkali metal halide should be shifted to the left as compared with the fluoride complexes. That is, lithium chloride does not react with chlorides of the rare-earth elements with the formation of any compounds the binary phase diagrams are characterized by one simple eutectic. The same situation is observed for the binary diagrams for lithium- and rare-earth bromides. 

Fen] Fenstad, J., Tuset, J.Kr., The Binary Diagrams wifliin die System Fe-Mn-C-O, and the Thermal Properties of Elemental Manganese , INFACON 9 Proceedings of the International Ferro-Alloys Congress, June 2001, Quebec, Canada, 9, 1-11 (2001) (Experimental, Phase Relations, Thermodyn., 25)... 

Fig. 38. Diagram comparing the optical characteristics of a standard binary chrome mask with a phase-shift mask. The changes in the electric fields introduced by the phase-shift elements result in a sharper light intensity profile at the wafer surface.

Figure 2. The connected schematic binary alloy phase diagrams for the light actinides. The diagrams for Ac through U and for AmCm are estimates based upon the pure elements.

Figure 2.27. Isothermal section at 307°C of the Al-Zn-Si diagram. The boundary binary systems are shown. The isothermal section at 307°C is marked on the binary Al-Zn diagram. The corresponding single-phase (thick segment) and two-phase regions are indicated in the base edge of the triangle. By additions of Si (immiscible in the solid state in the other two elements) two- and three-phase fields are formed. ( ) = three-phase region. In the two-phase region on the left examples of tie-lines are presented.

Several phase diagrams of binary alloy systems have been shown (see for instance Fig. 2.18) in which the existence of intermediate phases may be noticed. In these systems we have seen the formation of AmB phases, which generally crystallize with structures other than those of the constituent elements, and which have negligible homogeneity ranges. Thermodynamically, the composition of any such phase is variable. In a number of cases, as those exemplified in Fig. 2.19, the possible variation in composition is very small (invariant composition phases or... 

As a conclusion to this point, and in order to illustrate the variety of behaviour in the reactions of the different elements with hydrogen, a few phase diagrams of binary hydrogen systems can be considered. 

Figure 5.26. Iron binary alloys. Examples of the effects produced by the addition of different metals on the stability of the yFe (cF4-Cu type) field are shown. In the Fe-Ge and Fe-Cr systems the 7 field forms a closed loop surrounded by the a-j two-phase field and, around it, by the a field. Notice in the Fe-Cr diagram a minimum in the a-7 transformation temperature. The iron-rich region of the Fe-Ru diagram shows a different behaviour the 7 field is bounded by several, mutually intersecting, two (and three) phase equilibria. The Fe-Ir alloys are characterized, in certain temperature ranges, by the formation of a continuous fee solid solution between Ir and yFe. Compare with Fig. 5.27 where an indication is given of the effects produced by the different elements of the Periodic Table on the stability and extension of the yFe field.

Intermetallic chemistry of Be, Mg, Zn, Cd and Hg 5.12.4.1 Phase diagrams of the Be, Mg, Zn, Cd and Hg alloys. The systematics of the compound formation of these metals in their binary alloys with the different elements is summarized in Fig. 5.33. On the overall they give a rather complex picture even so a number of relationships and similarities between various pairs of metals may be singled out. To go into this point in more detail, in the same figure a comparison has also been made with the compound formation patterns of Ca and A1 which are described in 5.4 and 5.13 but are close in the Periodic Table to the metals here considered. The similarity between the Be and Zn patterns may be underlined, as also that between Be and Al, being an example of the so-called diagonal relationships presented in 4.2.2.2. 

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