BINAP molecular structure

SCHEME 35. Molecular structure of A-Ru(OCOCH3)2[( S)-binap]. [T. Ohta, H. Tak-aya, and R. Noyori, Inorg, Chem., 27, 566 (1988). Reproduced by permission of the American Chemical Society.]... 

Benzamido-cinnamic acid, 20, 38, 353 Benzofuran polymerization, 181 Benzoin condensation, 326 Benzomorphans, 37 Benzycinchoninium bromide, 334 Benzycinchoninium chloride, 334, 338 Bifiinctional catalysts, 328 Bifiinctional ketones, enantioselectivity, 66 BINAP allylation, 194 allylic alcohols, 46 axial chirality, 18 complex catalysts, 47 cyclic substrates, 115, 117 double hydrogenation, 72 Heck reaction, 191 hydrogen incorporation, 51 hydrogen shift, 100 hydrogenation, 18, 28, 57, 309 hydrosilylation, 126 inclusion complexes, oxides, 97 ligands, 19, 105 molecular structure, 50, 115 mono- and bis-complexes, 106 NMR spectra, 105 olefin isomerization, 96... 

Figure 3.1. Molecular structure of the cationic part in [ Rh((/ )(+)-BINAP) 3(0D)2]C104 ...

Figure 1 depicts a molecular view of [PdPh (R)-(BINAP) ]+ species which was drawn with the Chem 3D computer program using the partial X-ray structure of [PdCl2 (R)-BINAP ]. It is seen that the lower part of the empty coordination site widely opens whereas the upper part is blocked by one of the phenyl groups of the BINAP ligand. 

The crystal structure of the p-pinene allyl compound [Pd(T 3-CioHi5)(S-(+)-BINAP)]+[CF3S03]- has been determinedl39 and multinuclear NMR measurements and molecular mechanics calculations on the related compound [Pd(Ti3-C]oH s)(5,5-CHIRAPH0S)]+[CF3S03]- presentedl o. 

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