Bifunctional organomagnesium compounds

During studies on bifunctional organomagnesium compounds , the structures in the solid state of several such compounds were determined. Association measurements of magnesiacyclohexane in THF solution indicated that this compound is in equilibrium with a dimer. An X-ray crystal-structure determination of the product that crystallizes from... [Pg.40]

FIGURE 51. Bifunctional cychc organomagnesium compounds 103 and 104 in the sohd state... [Pg.41]

Bifunctional organomagnesium-halide reagents are investigated both for their inherent structural interest and as synthons for other organometallic or organic compounds. The smaller representatives are not easily available from the corresponding halides, because side reactions usually prevail their formation and chemistry are poorly known. [Pg.403]

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