Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Benzylacetic acid

Carbonylation of phenethyl bromide catalysed by Co2(CO)8 alone or modified either with tppts or tppms yielded products of double- and mono-carbonylation, (benzylpyruvic and benzylacetic acid, respectively) at a concentration of 8 mol% cobalt, 85°C and 20 bar CO under basic conditions in an H20/tBuOH (14/1) solvent mixture (Figure 13).475>476 The reaction rates exhibited by Co2(CO)8 were comparable with the Co2(CO)6(tppts)2 catalyst but replacement of tppts by tppms gave rise to a dramatic decrease in catalytic activity.475 Substantially different double/mono carbonylation (d/m ratios) were observed with Co2(CO)8, Co2(CO)e(tppts)2 and Co2(CO)6(tppms)2 7.3, 2.1 and 0.3, respectively, which... [Pg.160]

W C HggH -ICH OOHl Benzylacetic acid, 3-Phenylpropanoic acid OH... [Pg.332]

So far, easily available alkyl halides have not been applied to biphasic carbonyla-tions. However, the carbonylation of phenethyl bromide with hydrophilic cobalt catalysts to give benzylpyruvic acid (BPA) and benzylacetic acid (BAA) was investigated (Eq. 11) [21]. [Pg.507]

Beilstein Handbook Reference) AI3-00892 Benzenepropanoic acid Benzeneproplonic acid Benzylacetic acid BRN 0907515 CCRIS 3199 Dihydrocinnamic acid EINECS 207-924-5 FEMA No. 2889 Hydrocinnamic acid NSC 9272 Phenylpropanoic acid 3-Phenylpropanoic acid p-Phenylpropionic acid 3-Phenylpropionic acid. Fixative for perfumes, flavoring. Solid mp = 47-48° bp n 280° Xm = 247, 252, 257, 260, 263, 267 nm (MeOH) soluble in H2O (5.8 g/l), EtOH, Et20, CCl4, CHCI3, CS2, very soluble in CeHe, Greeff R.W. Co. Janssen Chimica Penta Mfg. [Pg.326]

Benzylacetic acid. See Hydrocinnamic acid Benzyl acetoacetate... [Pg.464]

Synonyms Benzenepropanoic acid Benzenepropionic acid Benzylacetic acid Dihydrocinnamic acid Phenylpropanoic acid 3-Phenylpropanoic acid Phenylpropionic acid 3-Phenylpropionic acid P-Phenylpropionic acid... [Pg.2062]

Mono- and double carbonylation of phenetyl bromide with cobalt-phosphine catalysts afforded benzylacetic (Baa) and benzylpymvic (Bpa) acids respectively [23] (Scheme 5.5). The highest yield of benzylpymvic acid (75 %) was obtained with [Co2(CO)8], while addition of the water soluble phosphines TPPMS or TPPTS decreased both the yield of carbonylated products and the selectivity to Bpa. [Pg.151]


See other pages where Benzylacetic acid is mentioned: [Pg.344]    [Pg.332]    [Pg.371]    [Pg.343]    [Pg.611]    [Pg.332]    [Pg.813]    [Pg.198]    [Pg.244]    [Pg.1045]    [Pg.198]    [Pg.483]    [Pg.224]    [Pg.344]    [Pg.332]    [Pg.371]    [Pg.343]    [Pg.611]    [Pg.332]    [Pg.813]    [Pg.198]    [Pg.244]    [Pg.1045]    [Pg.198]    [Pg.483]    [Pg.224]    [Pg.321]   
See also in sourсe #XX -- [ Pg.123 , Pg.198 ]




SEARCH



Benzylacetate

© 2024 chempedia.info