Benzenediazonium nitrate

N 31.09%, yel prisms, mp explds. Was prepd by Griess (Ref 2) by adding a cold satd aq soln of benzenediazonium nitrate to ammonia. Insol in w, sol in ale and eth with deoompn. In the dry state, it explds violently when heated, or on impact or friction... [Pg.609]

Amino-3-phenyl-1,2,4-triazole, Nitrous acid, 2952 Benzenediazonium chloride, 2230 Benzenediazonium iodide, 2250 Benzenediazonium nitrate, 2275... [Pg.116]

Ammonium hexacyanoferrate(II), 2577 f Arsine, 0100 Azido-2-butyne, 1473 3-Azidopropyne, 1114 c /.v-A/obcn/cnc, 3484 Azoxybenzene, 3485 Barium azide, 0214 Benzenediazonium nitrate, 2275 Benzotriazole, 2269 Borane, 0135 Bromine azide, 0256 f 3-Bromopropyne, 1090 f 1,2-Butadiene, 1479 f 1,3-Butadiene, 1480 f Buten-3-yne, 1423 f 1-Butyne, 1481 f 2-Butyne, 1482 Cadmium azide, 3957 Cadmium cyanide, 0588 Cadmium fulminate, 0589 Cadmium nitride, 3960... [Pg.139]

Benzenediazonium Tribromide (Diazobenzene Tribromide), CsHs.N2.Br3 mw 264.95, N 10.58% orn-red ndls, mp 63-5°(dec), expl weakly on heating diffc sol in cold ale insol in w or erh. Can be prepd by treating a benzenediazonium chloride soln with an aq K bromide soln and by reacting bromine in a hydrobromic acid soln with a soln of benzenediazonium nitrate or sulfate. The dry comp is stable but in a humid atm it dec into 2,-4,6-tribromophenol. It rapidly dec in the presence of ale... [Pg.58]

Dinitro-l-chlorobenzene or 1,3-Dinitro-2 chlorobenzene, yel nds(from ale), mp 87.8°, d 1.6867 at 16.5° sol in ale 8c eth insol in w forms in small quantities during heating of o-chloronitrobenz with mixed acid, or can be prepd from 2,6-benzenediazonium nitrate CuCl2(Refs 1, 2 5). A new method of prepg 2,6-DNCB is reported by Molard Vaganay (Ref 11)... [Pg.32]

The first volume of the Memorial des Poudres et Salpetres contains a report by Berthelot and Vieille04 on the properties of benzenediazonium nitrate (diazobenzene nitrate). They prepared the material by passing nitrous gas into a cooled aqueous solution of aniline nitrate, diluting with an equal volume of alcohol, and precipitating in the form of white, voluminous flocks by the addition of an excess of ether. [Pg.442]

Benzenediazonium nitrate detonates easily from the blow of a hammer or from any rubbing which is at all energetic. It explodes violently when heated to 90°. Its density at 15° is 1.37, but under strong compression gently applied it assumes an apparent density of 1.0. Its heat of formation is —47.4 Calories per mol, heat of explosion 114.8 Calories per mol. [Pg.442]

Benzenediazonium-2-carboxylate, 2655 Benzenediazonium-3-carboxylate, 2656 Benzenediazonium-4-carboxylate, 2657 Benzenediazonium chloride, 2223 Benzenediazonium hydrogen sulfate, 2311 Benzenediazonium iodide, 2243 Benzenediazonium nitrate, 2268 Benzenediazonium-4-oxide, 2182 Benzenediazonium perchlorate, 2225 Benzenediazonium-2-sulfonate, 2185 Benzenediazonium-4-sulfonate, 2186 Benzenediazonium tetrachlorozincate, 3469 Benzenediazonium tetrafluoroborate, 2216 Benzenediazonium tetraphenylborate, 3870a Benzenediazonium tribromide, 2220 Benzenediazonium triiodide, 2247... [Pg.2049]

Trinitro-5 -chlorobenzene, yel-crysts (from ale), mp 116° can be prepd by treating 5 -chloro-2,4-dinitro-l-benzenediazonium nitrate with Na nitrite in w or by other methods. [Pg.32]

The conversion may consist simply in oxidation or be the result of a more complex reaction. For example, nitrosotoluene can be converted into diazonium nitrate under the influence of nitrous acid. Bamberger [132] found in 1918 that nitrosobenzene could be converted into benzenediazonium nitrate under the influence of nitrous acid. According to Bamberger [133] and Nesmeyanov [134], mercury-aromatic compounds also give nitrates of corresponding diazonium compounds under the influence of N203, presumably also through nitroso compounds. [Pg.112]

Dinitro-2.6-dibromobenzene, prisms (from ale), mp 130° prepd from 4-nitro-2,6-dibromo-benzenediazonium nitrate NaN02 soln at 0°(Ref 7)... [Pg.86]

Synthesis of diazonium salts. Scribner found that addition of dinitrogen tetroxide to an ethereal solution of the Schiff base benzylidene aniline gives a precipitate of anhydrous benzenediazonium nitrate (highly explosive). [Pg.167]

Benzenediazomum-2-carboxylate, 46,1194 Benzenediazonium chloride, 394, 838 Benzenediazonium fluoroborate, 394 Benzenediazonium nitrate, 328 Benzenediazonium sulfonate, 713 Benzene-maleic anhydride 1 2 adduct, 557 Benzenesulfinyl fluoride, 849 Benzenesulfonamides, 46-47, 48... [Pg.699]

Azidopropyne, 1114 c/.s-Azobcnzcuc, 3484 Azoxybenzene, 3485 Barimn azide, 0214 Benzenediazonium nitrate, 2275 Benzotriazole, 2269 Borane, 0135 Bromine azide, 0256... [Pg.2243]

Benzenediazonium nitrate [619-97-6] Benzenediazonium-4-sulphonate [2154-66-7] Bis(5-chlorotoluenediazonium) zinc tetrachloride [89453-69-0] o- and m-Chlorobenzenediazonium salts (e.g. [89-90-7], [100-77-6]) 4-Chloro-2-methylbenzenediazonium salts (e.g. [94-95-1]) Di(benzenediazonium) zinc tetrachloride [69092-42-8]... [Pg.216]

An ethereal soln. of N-benzylideneaniline added to an ice-cooled ethereal soln. of dinitrogen tetroxide, stirred 0.5 hr. in the cold, and allowed to stand overnight at room temp. benzenediazonium nitrate (explosive ). Y 90%. R. M. Scribner, J. Org. Ghem. 29, 3429 (1964). [Pg.372]

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