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Behavioural factors probability

The exact interpretation of this behaviour is complex. In essence, however, it may be regarded as due to the competing effects of the reduction in solvent density and the increase in solute volatility which accompany the temperature rise. At pressures below about 300 bar, density decreases comparatively rapidly with isobaric increase in temperature, in the temperature range of interest, and it is the effect of this factor on solubility which predominates. At higher pressures than this the influence of temperature on density becomes less marked and an increase in solubility with temperature occurs. This behaviour is probably typical of solutes of very low solubility. [Pg.21]

As early as 1972, Kuhn described a model in which he assumed that RNA replication with a certain error rate could have occurred without the participation of enzymes. Natural phenomena with cyclic behaviour are an important factor in Kuhn s thinking these drive duplication processes. Examples are summer and winter, day and night, or high and low tide (whereby the latter were probably subject to greater variations on the primeval Earth than they are today). These rhythms were often linked with considerable temperature variations, which, for example, made possible the transition from double to single strand RNA (and vice versa). It can be assumed that the cyclic variations involved reactions in which monomers were linked to form polymers. [Pg.228]

It is clear that these solvolytic reactions of ipso-adducts are markedly dependent on reaction conditions strongly acidic conditions and electron withdrawing substituents will favour a heterolytic process lower acidity, higher temperatures and electron releasing substituents probably favour homolytic processes. With so many factors involved, each substrate under each set of conditions gives rise to its own particular behaviour. [Pg.961]

A further factor that probably affected the parent s contact with children was the angry or cold reception they might receive when they did appear in the family home because of their drug use and its effects on all their lives. Also, pre-existing and unresolved family difficulties would be part of the dynamic and would find a focus in the parent s drug-related behaviours so that conflict would be very likely when they visited. Whatever the problem drug-using parent s rationale for infrequent visits, however, their children found it hard to live with the disappointment ... [Pg.113]

Fig. 18. Reciprocal particle-scattering factors of star-molecules with polydisperse rays, where f denotes the number of rays per molecule. The same functions are obtained also for the ABC-type polycondensates, where nb denotes the number of branching points per molecule. The case f = 1 or nb = 0 is identical to linear chains obeying the most probable lengths distribution. It also represents the scattering behaviour of randomly branched f-functional polycondensates 1... Fig. 18. Reciprocal particle-scattering factors of star-molecules with polydisperse rays, where f denotes the number of rays per molecule. The same functions are obtained also for the ABC-type polycondensates, where nb denotes the number of branching points per molecule. The case f = 1 or nb = 0 is identical to linear chains obeying the most probable lengths distribution. It also represents the scattering behaviour of randomly branched f-functional polycondensates 1...

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See also in sourсe #XX -- [ Pg.267 ]




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