Atomizer designs

File 4-.5. An Approximate Input File for the Water Molecule. A hydrogen attached to an oxygen has the special atom designator 21 as distinct from the designator. n in hydrocarbons. 

Many empirical correlations have been pubHshed in the Hterature for various types of Hquid atomizers, eg, one book (2) provides an extensive coUection of empirical equations. Unfortunately, most of the correlations share some common problems. Eor example, they are only vaHd for a specific type of atomizer, thereby imposing strict limitations on thein use. They do not represent any specific physical processes and seldom relate to the design of the atomizer. More important, they do not reveal the effect of interactions among key variables. This indicates the difficulty of finding a universal expression that can cover a wide range of operating conditions and atomizer designs. 

Using equations 11 and 12, the estimated Sauter mean diameters agree quite weU with experimental data obtained for a wide range of atomizer designs. Note that the two constants in equation 11 differ from those shown in Lefebvre s equation (32). These constants have been changed to fit a wide range of experimental data. 

Types of atomizer Design features Advantages Disadvantages... 

M0S2CI3, monoclinic (P2i/c). Figure 23 shows the translational unit, with atom designations. The sulfur atoms form pairs having a distance of 1.98 A. The molybdenum atoms also occur in pairs enclosed by two bridging S2 groups. With two chlorine atoms in terminal and... 

The S-N unit is the thiazyl group and S4N3+ contains three of these units plus one sulfur atom (designated as thio) hence the name. When S4N4 reacts with NOC1, a five-membered ring is produced. 

Atomization of melts has been used in two principal areas, i.e., powder production 4] and spray forming, 3] as shown in Figs. 1.4 and 1.5, respectively. It is not until recent years that the technologies for the atomization of melts have advanced sufficiently to ensure good yields of usable products over sustained periods of plant operation. In these two areas, some aspects such as melting of metals or alloys, basic atomizer designs, and atomization mechanisms are the same or similar. Metals or alloys melt at high temperatures to produce low viscosity but usually... 

Figure 2.8. Schematic of Parker Hannifin atomizer designed for atomizing coal-water slurries and other difficult-to-atomize liquids. (Courtesy of Parker Hannifin Corporation, USA.)...

A variety of atomizer designs have been developed in an effort to control the droplet size distribution and to increase the yield of fine powders. Gas atomizers used for the atomization of melts may be loosely classified into two primary categories in terms of the interaction mode between a liquid metal and an atomization gas during atomization, i.e., (1) internal mixing and (2) external mixing. 

Droplet Formation in Water Atomization. In water atomization of melts, liquid metal stream may be shattered by impact of water droplets, rather than by shear mechanism. When water droplets at high velocities strike the liquid metal stream, some liquid metal fragments are knocked out by the exploding steam packets originated from the water droplets and subsequently contract into spheroidal droplets under the effect of surface tension if spheroidization time is less than solidification time. It is assumed that each water droplet may be able to knock out one or more metal droplet. However, the actual number of metal droplets produced by each water droplet may vary, depending on operation conditions, material properties, and atomizer designs. 

As described above, a number of empirical and analytical correlations for droplet sizes have been established for normal liquids. These correlations are applicable mainly to atomizer designs, and operation conditions under which they were derived, and hold for fairly narrow variations of geometry and process parameters. In contrast, correlations for droplet sizes of liquid metals/alloys available in published literature 318]f323ff328]- 3311 [485]-[487] are relatively limited, and most of these correlations fail to provide quantitative information on mechanisms of droplet formation. Many of the empirical correlations for metal droplet sizes have been derived from off-line measurements of solidified particles (powders), mainly sieve analysis. In addition, the validity of the published correlations needs to be examined for a wide range of process conditions in different applications. Reviews of mathematical models and correlations for... 

Thus, both the mean droplet size and the size distribution may be predicted using these correlations [Eqs. (26), (27), (28), or (29) and Eqs. (30), (31)] for given process parameters and material properties. For a given atomizer design, the standard deviation of droplet size distribution has been found to increase with the melt flow rate, but appears to be less sensitive to the gas flow rated5 Moreover, the variation of the standard deviation is very atomizer- and melt-specific. An empirical correlation which fits with a wide range of atomization data has the following form ... 

Figure 2.7 Structure of adenosine tn phosphate. The molecule consists of adenine attached to ribose (forming adenosine) which is esterified to a triphosphate group with the three phosphorus atoms designated a, p and y. The primes ( ) on the carbon atoms of ribose differentiate the numbers from those of the adenine ring.

The goethite structure contains two types of O atoms designated as Oi and On (Fig. 2.4e). On the 0 site, the O atom is shared between octahedra of two different double chains, whereas the On atom is shared between octahedra in the same chain and is also linked to the proton. Neutron scattering has shown that the On-On distance is... 

Fig. 19. (a) Atomic designations and (b) stereo view of azurin. Cu(II) [2N, 2S, O]. In this and Figs. 20-35 oxygen atoms are stippled, nitrogen atoms are black, and carbon atoms are white. Generally, hydrogen atoms are not included, but if they are, they are represented by smaller circles. 

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