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Atomization automizer selection

In general, gas chromatography will undoubtedly continue to be the method of choice for characterization of light hydrocarbon materials. New and improved detection devices and techniques, such as chemiluminescence, atomic emission, and mass spectroscopy, will enhance selectivity, detection limits, and analytical productivity. Laboratory automation through autosampling, computer control, and data handling will provide improved precision and productivity, as well as simplified method operation. [Pg.252]

The most important features of liquid membranes are that they olfer highly selective extraction, efficient enrichment of analytes from the matrix in only one step, and the possibility of automated interfacing to different analytical instruments such as liquid chromatography, gas chromatography, capillary zone electrophoresis, UV spectrophotometry, atomic absorption spectrometry, and mass spectrometry [82]. [Pg.578]

The selective electrophilic aromatic substitution carried out by displacement of a metallic substituent (Hg, Sn) ( F-fluorodemetallation) using [ F]p2 or [ F]AcOF remains a method of choice to introduce a fluorine atom on a specific position. In the early preparations of [6- F]fluoro-L-DOPA, the reaction of a 6-substituted mercuric derivative with [ F]acetyl hypofluorite yielded the expected compound in 11 % yield [73,74]. Reaction of a mercuric precursor, free or on a modified polystyrene support P-CH2-COOHg(DOPA precursor) allows the preparation of [ F]fluoro-L-DOPA in an overall yield up to 23 %. The polymer supports are easily prepared, require no special treatment for storage and are convenient to use in automated production [75]. [Pg.214]

In spite of its limited sensitivity, colorimetry is still useful in determination of elemental concentrations in the g range or higher (Seiler, 1988). Its main advantage is that the needed instrument, a spectrophotometer, is common in every laboratory. Colorimetric trace metal determinations are based, commonly after sample decomposition, on selective separations from interfering ions (Abbasi et al., 1988). Automated colorimetric procedures are described for the determination of N and P in trees (Stewart et al., 1990). Modern spectrophotometers provide high stability, low noise, and the advantages of computerised background control. However, for total metal determinations in environmental samples, this method is less frequently applied and has been replaced by atomic spectroscopic and electrochemical methods (Stoeppler, 1991). [Pg.258]

The concentration of lithium in serum, plasma, urine, or other body fluids has been determined by flame emission photometry, atomic absorption spectrometry, or electro-chemically using an ion-selective electrode. Serum analysis, the most useful specimen for lithium monitoring, is most commonly quantified by automated spectrophotometric assay. [Pg.1272]

Total calcium is most frequently measured by spectrophotometry using metaUochromic indicators or dyes. Of the metaUochromic indicators that change color on selectively binding calcium, o-cresolphthalein complexone (CPC) (3, 3"-bis [ [bis-(carboxymethyl)amino] -methyl] -5", 5"-dimethylphenolphthalein) (Figure 49-3) and arsenazo III are most widely used. These methods, although less accurate and reproducible than atomic absorption spectrophotometry, have been easier to automate on chemistry analyzers. [Pg.1897]

According to this equation, Xu and coworkers developed a method to generate hypothetical open-framework aluminophosphate structures with specified Al/P stoichiometry using the automated assembly of SBUs.[76] For each specified Al/P stoichiometry, all the possible combinations of A1 and P atoms with different coordination states could be calculated according to Equation (3.2). The A1 and P atoms of different coordination states, together with the clusters constructed by them, could be selected as the building... [Pg.156]

If the product is needed on a small scale, up to 100 g, the reaction can be scaled out rather than scaled up. The excellent reproducibihty together with automation can easily produce up to 100 g overnight. Bose et al. have described an alternative for minor scale-up where the use of the microwave-assisted organic reaction enhancement (MORE) technique reduces the need for organic solvents and increases atom economy by improving product selectivity and chemical yield, thus, minimizing the need for larger scale-up. [Pg.413]


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See also in sourсe #XX -- [ Pg.232 , Pg.233 , Pg.234 , Pg.235 ]




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