Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Atomic oxygen redox thermodynamics

A recent discussion concludes that high-valent transition metal ions such as iron(IV) are thermodynamically incompatible with the strongly electronegative 0x0 dianion, particularly when electron transfer results in unpaired valence electrons that can stabilize each other via covalent bond formation. Such stabilization of the two unpaired electrons of ground-state atomic oxygen attenuate its redox potential and it reactivity to an extent proportional to the energy of the metal-oxygen covalent bond. [Pg.140]

See other pages where Atomic oxygen redox thermodynamics is mentioned: [Pg.23]    [Pg.151]    [Pg.213]    [Pg.311]    [Pg.267]    [Pg.269]    [Pg.463]    [Pg.244]    [Pg.438]    [Pg.71]    [Pg.140]    [Pg.8]    [Pg.569]    [Pg.356]    [Pg.1246]    [Pg.1279]    [Pg.4055]    [Pg.491]    [Pg.290]    [Pg.18]    [Pg.8]    [Pg.182]    [Pg.290]    [Pg.112]    [Pg.113]    [Pg.303]    [Pg.412]    [Pg.917]    [Pg.92]    [Pg.101]    [Pg.89]    [Pg.32]    [Pg.466]    [Pg.183]    [Pg.184]   
See also in sourсe #XX -- [ Pg.23 , Pg.24 , Pg.25 ]



SEARCH



Oxygen atom

Oxygen atomic

Oxygen thermodynamics

Redox oxygen

Redox thermodynamics of atomic oxygen

© 2024 chempedia.info