Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Asymptotic properties theorem

The asymptotic properties of fn (x) are determined by Fisher s theorem. Note that the values x S> 1 correspond, for the chain, to stretched configurations. [Pg.88]

Many important properties, such as critical dimensionality and critical exponents describing the divergence of correlation length and other quantities can thus be obtained from renormalization group analysis. It is worth noting that for X well below X only the quadratic terms of the potential contribute to the asymptotic properties of P, which reduces therefore to a multigaussian distribution in accordance with the central limit theorem [13]. There exists,however,a (frequently very narrow) vicinity of X ... [Pg.186]

Levy identified the unknown part of the exact universal D functional as the correlation energy Ed D] and investigated a number of properties of c[ D], including scaling, bounds, convexity, and asymptotic behavior [11]. He suggested approximate explicit forms for Ec[ D] for computational purposes as well. Redondo presented a density-matrix formulation of several ab initio methods [26]. His generalization of the HK theorem followed closely Levy s... [Pg.390]

Many problems appear to be ripe for a more quantitative discussion. What is the error involved in the introduction of unstable states as asymptotic states in the frame of the 5-matrix theory 16 What is the role of dissipation in mass symmetry breaking What is the consequence of the new definition of physical states for conservation theorems and invariance properties We hope to report soon about these problems. We would like, however, to conclude this report with some general remarks about the relation between field description and particles. The full dynamical description, as given by the density matrix, involves both p0 and the correlations pv. However, the particle description is expressed in terms of p (see Eq. (50)). Now p has only as many elements as p0. Therefore the... [Pg.34]

In conclusion, the ordinary central limit theorem (CLT) establishes that all the propagators sharing the same second moment (c2) yields in the time asymptotic limit the same gaussian pdf. What is the property that the propagators with a diverging second moment must have in common to produce the same pdf in the time asymptotic limit The answer to this question is equivalent to establishing the GCLT [45]. The answer to this important question rests on the anti-Fourier transform of the expression of Eq. (102), which turns out [46] to yield for v oc a distribution proportional to 1/ E,, with... [Pg.387]

According to this theorem, a solution of Eg. (3) may be computed by tracing a trajectory of the system of differential equations (56) till it approaches a constant solution curve that corresponds to a stationary point of E. Since the asymptotical stability is a local property, a curve emanating from x will approach an asymptotically stable solution xsx of Eg. (55a) with reliability only if x and w belong to the stability domain of that solution function. Thus, theoretically the situation is similar to that of Newton s method. In practice, however, most trajectories flow into a stability domain. So a curve tracing represents a systematic search. This is a considerable advantage for the computational practice. [Pg.74]

The statistical properties of the random force f(0 are modeled with an extreme economy of assumptions f(t) is assumed to be a stationary and Gaussian stochastic process, with zero mean (f(0 = 0), uncorrelated with the initial value v(t = 0) of the velocity fluctuations, and delta-correlated with itself, f(0f(t ) = f25(t -1 ) (i.e it is a purely random, or white, noise). The stationarity condition is in reality equivalent to the fluctuation-dissipation relation between the random and the dissipative forces in Equation 1.1, which essentially fixes the value of y. In fact, from Equation 1.1 and the assumed properties of f(t), we can derive the expression y(f)v(t) = exp [v(0)v(0) -+ ylM °, where Xg = In equilibrium, the long-time asymptotic value y/M must coincide with the equilibrium average (vv) = (k TIM)t given by the equipartition theorem (with I being the 3 X 3 Cartesian unit tensor), and this fixes the value of y to y=... [Pg.6]


See other pages where Asymptotic properties theorem is mentioned: [Pg.152]    [Pg.413]    [Pg.33]    [Pg.182]    [Pg.391]    [Pg.156]    [Pg.166]    [Pg.41]    [Pg.204]    [Pg.163]    [Pg.1027]    [Pg.21]    [Pg.22]    [Pg.53]    [Pg.112]    [Pg.167]    [Pg.170]    [Pg.271]    [Pg.64]   
See also in sourсe #XX -- [ Pg.2 , Pg.41 , Pg.42 ]




SEARCH



Asymptotes

Asymptotic

Asymptotic property

Asymptotically

Asymptotics

© 2024 chempedia.info