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Asymptotic analysis equilibrium approach

Even for potential energy the other approach [93] required one parameter additional to oiu-s, apart from Dq, the latter quantity, equilibrium binding energy, is stated to be based on thermochemical data, but the cited source [95] indicates a value of dissociation energy 29q <2.84eV to arise from spectral analysis. Such an upper limit must be understood to provide an asymptotic limit for V(i ) at large i in a formula of Morse type because an attempted evaluation of 29e from only infrared spectral data is unreliable. The stated reason for the choice... [Pg.285]

HPTS fluorescence has been employed in the study of proton diffusion within inverted micelles [24], in liposomes [4a], in apomyoglobin and the inter-membranal hydration layers of multi-lamellar vesicles [4b]. The simplest case for analysis involves the HPTS molecule in the center of a sphere (inverted micelle, liposome) whose walls are impermeable to protons on the timescale of the experiment. This outer wall is therefore described by an additional reflective boundary condition. Inside such a sphere, even a single proton/anion pair ultimately reaches an equilibrium situation The long-time tail approaches a plateau, rather than decaying to zero. The smaller the radius of the sphere, the higher the expected asymptotic plateau. [Pg.332]


See other pages where Asymptotic analysis equilibrium approach is mentioned: [Pg.113]    [Pg.64]    [Pg.331]    [Pg.311]    [Pg.430]    [Pg.12]    [Pg.64]    [Pg.430]    [Pg.308]    [Pg.333]    [Pg.12]    [Pg.64]    [Pg.154]    [Pg.64]    [Pg.426]    [Pg.81]    [Pg.64]    [Pg.202]    [Pg.329]    [Pg.101]   
See also in sourсe #XX -- [ Pg.367 ]




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