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Aryl peroxy radicals

Aryl peroxy radicals may not be as effectively converted because the... [Pg.320]

The reaction stoichiometries, product profiles, and apparent second-order rate constants for the combination of perfluoroaromatic molecules (and several hydro and dihydro derivatives) with excess superoxide ion in dimethylformamide are summarized in Table 7-1. The primary product from the combination of C6F6 with 2 equivalents of O2-- is CeEgOO on the basis of the F-NMR spectrum of the product solution and the mass spectrum for the major peak from the capillary GC of the product solution.24 Similar analyses of the product solutions for the other fluoro substrates are consistent with a peroxide product from the displacement of a fluoride ion. A reasonable first step for these oxygenations is nucleophilic addition of O2 - to the polyfluoroaromatic. Subsequent loss of fluoride ion will give an aryl peroxy radical, which will be reduced by a second O2-- to the aryl peroxide product. This reaction sequence (with the initial nucleophilic displacement the rate-determining step) is analogous to that observed for chlorohydrocarbons and polychlorobenzenes (Scheme 7-8). However, the peroxo product of the latter systems is an effective nucleophile that attacks a second substrate molecule (or an adjacent aryl chlorine... [Pg.170]

Antioxidants markedly retard the rate of autoxidation throughout the useful life of the polymer. Chain-terminating antioxidants have a reactive —NH or —OH functional group and include compounds such as secondary aryl amines or hindered phenols. They function by transfer of hydrogen to free radicals, principally to peroxy radicals. Butylated hydroxytoluene is a widely used example. [Pg.1008]

Recently, sulfinyl and sulfonyl peroxy radical intermediates 6a and 6b have been prepared by the reactions of aryl sulfinyl or sulfonyl chloride with superoxide anion radical, respectively. These peroxy intermediates show strong oxidizing abilities in various oxidations. This chapter will describe the properties and applications of a variety of sulfur and phosphorus peroxy compounds in oxidation reactions. For a more complete picture, readers should consult the original papers cited in the areas that most interest them. [Pg.1002]

Photolysis has more commonly been effected by electromagnetic radiation. For example, Ingold and Morton (1964) have irradiated t-butyl hydroperoxide and cumyl hydroperoxide and observed the corresponding peroxy radicals, ROa (gr 2-014), where R=Me3C and PhCMea. Maruyama et al. (1964) have obtained the spectra of aryl-substituted nitroxide radicals, AraN—0-, by irradiating aromatic nitroso-compounds, ArNO and Strom and Bluhm (1966) have similarly... [Pg.64]

Hindered phenols and secondary aryl amines act as primary antioxidants by donating their reactive hydrogen (N-H, O-H) to free radicals, particularly peroxy radicals as shown here ... [Pg.440]


See other pages where Aryl peroxy radicals is mentioned: [Pg.230]    [Pg.230]    [Pg.264]    [Pg.68]    [Pg.87]    [Pg.112]    [Pg.164]    [Pg.207]    [Pg.252]    [Pg.900]    [Pg.207]    [Pg.252]    [Pg.900]    [Pg.107]    [Pg.45]    [Pg.210]    [Pg.262]    [Pg.156]    [Pg.693]    [Pg.238]    [Pg.104]    [Pg.158]    [Pg.158]    [Pg.107]    [Pg.242]    [Pg.158]    [Pg.38]    [Pg.73]    [Pg.150]    [Pg.74]   
See also in sourсe #XX -- [ Pg.230 ]




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