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Arenes addition reactions

An analogous regioselective effect of silver ions on an addition reaction of arene-diazonium ions was found by Ignasiak et al. (1975) with cyanide salts. Potassium cyanide yields diazocyanides (Ar— N2 — C = N see Sec. 6.6), i.e., C-coupling products, but with silver cyanide - albeit in low yield (7-9%) - diazoisocyanides (Ar—N2 — N = C) are formed (a better synthesis of diazoisocyanides is described in Sec. 6.4). [Pg.109]

Abstract The photoinduced reactions of metal carbene complexes, particularly Group 6 Fischer carbenes, are comprehensively presented in this chapter with a complete listing of published examples. A majority of these processes involve CO insertion to produce species that have ketene-like reactivity. Cyclo addition reactions presented include reaction with imines to form /1-lactams, with alkenes to form cyclobutanones, with aldehydes to form /1-lactones, and with azoarenes to form diazetidinones. Photoinduced benzannulation processes are included. Reactions involving nucleophilic attack to form esters, amino acids, peptides, allenes, acylated arenes, and aza-Cope rearrangement products are detailed. A number of photoinduced reactions of carbenes do not involve CO insertion. These include reactions with sulfur ylides and sulfilimines, cyclopropanation, 1,3-dipolar cycloadditions, and acyl migrations. [Pg.157]

Arenes are unsaturated but, unlike the alkenes, they are not very reactive. Whereas alkenes commonly take part in addition reactions, arenes undergo predominantly substitution reactions, with the TT-bonds of the ring left intact. For example, bromine immediately adds to a double bond of an alkene but reacts with benzene only in the presence of a catalyst—typically, iron(III) bromide—and it does not affect the bonding in the ring. Instead, one of the bromine atoms replaces a hydrogen atom to give bromobenzene, C H Br ... [Pg.862]

Alkyl radical addition reactions to styrene chromium tricarbonyl can be accomplished using alkyl halides (10 equiv) and (TMSlsSiH (5 equiv) in the presence of AIBN in refluxing benzene, for 18 h (Reaction 66). " These reactions are believed to proceed through intermediates in which the unpaired electron is interacting with the adjacent arene chromium tricarbonyl moiety since the analogous reaction with styrene affords only traces of addition products. [Pg.148]

Organometals and metal hydrides as electron donors in addition reactions 245 Oxidative cleavage of carbon-carbon and carbon-hydrogen bonds 253 Electron-transfer activation in cycloaddition reactions 264 Osmylation of arene donors 270... [Pg.193]

Many related complexes of iridium and rhodium undergo the oxidative addition reaction of alkanes and arenes [1]. Alkane C-H bond oxidative addition and the reverse reaction is supposed to proceed via the intermediacy of c-alkane metal complexes [4], which might involve several bonding modes, as shown in Figure 19.5 (for an arene the favoured bonding mode is r 2 via the K-electrons). [Pg.390]

As well as organic chiral auxiliaries, organometallic fragments have found some application as chiral auxiliaries in conjugate addition reactions. Particularly noteworthy are chiral molybdenum allyl complexes [69], chiral iron complexes [70], and planar chiral arene chromium species [71]. [Pg.209]


See other pages where Arenes addition reactions is mentioned: [Pg.369]    [Pg.39]    [Pg.13]    [Pg.107]    [Pg.82]    [Pg.88]    [Pg.276]    [Pg.240]    [Pg.166]    [Pg.391]    [Pg.166]    [Pg.153]    [Pg.119]    [Pg.231]    [Pg.1072]    [Pg.1073]    [Pg.403]    [Pg.407]    [Pg.409]    [Pg.411]    [Pg.413]    [Pg.415]    [Pg.417]    [Pg.419]    [Pg.421]    [Pg.423]    [Pg.425]    [Pg.427]    [Pg.429]    [Pg.431]    [Pg.433]    [Pg.435]    [Pg.437]    [Pg.439]    [Pg.441]    [Pg.443]   
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See also in sourсe #XX -- [ Pg.531 , Pg.532 , Pg.533 , Pg.534 , Pg.535 , Pg.536 , Pg.537 , Pg.538 , Pg.539 , Pg.540 , Pg.541 , Pg.542 , Pg.543 , Pg.544 , Pg.545 , Pg.546 ]

See also in sourсe #XX -- [ Pg.4 , Pg.531 , Pg.532 , Pg.533 , Pg.534 , Pg.535 , Pg.536 , Pg.537 , Pg.538 , Pg.539 , Pg.540 , Pg.541 , Pg.542 , Pg.543 , Pg.544 , Pg.545 , Pg.546 ]

See also in sourсe #XX -- [ Pg.397 , Pg.398 ]

See also in sourсe #XX -- [ Pg.4 , Pg.531 , Pg.532 , Pg.533 , Pg.534 , Pg.535 , Pg.536 , Pg.537 , Pg.538 , Pg.539 , Pg.540 , Pg.541 , Pg.542 , Pg.543 , Pg.544 , Pg.545 , Pg.546 ]




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