2- -1 -anilino trans

C1I2)4- 4-CH, Cyclohexen trans-2-(4-Methyl-anilino) -1-phenylthio-cyclohexan 80... 

NO, Cyclohexen trans-2- (4-Nitro-anilino j-l -phenylthio-cyclohexan 94... 

H3C6-NH2/l,4-Dioxan, 90% 1-3 h dann isolieren 2. N2H4 H20/Raney-Ni/H3C-0H 20 25% 1 h NH—C6H5 NH2 [2-Anilino-l-phthalimidoamino-cyclohexan - ] trans-2-Amino-1-anilino-cydo-hexan [78] 83 1... 

For 9-phenylamino-6,7,8,9-tetrahydro-4//-pyrido[l,2-a]pyrimidin-4-ones 32 (R = NHPh R1 = H R2 = H, COOH) the half-chair conformation with a pseudoaxial 9-phenylamino group was the predominant one. But with the 6-methyl-9-phenylamino derivatives 32 (R = NHPh, R1 = Me) the cis-trans ratio was near 1 1 in the imine form. The presence of a methyl group on the nitrogen atom of the 9-anilino group 32 (R = NMePh) increased the amount of the cis form which contained the 9-substituent in a pseudoequatorial position [85JCS(P1)1015]. The 6-methyl group was in a pseudoaxial position in all tautomers. 

Harger, M.J.P., and Williams, A., Reactions of iV-phenyl a-halogenophosphonamidates with alkoxide. Migration of the anilino group from phosphorus to the a carbon atom, J. Chem. Soc., Perkin Trans. 1, 1681, 1986. 

Benzyliden-anilin ergibt mit Kupfer/N,N-Diathyl-dithiocarbaminsaure trans-l,2-Di-anilino-1,2-diphenyl-dthan1 ... 

Capping of one side of the torus with an apolar moiety enhances the binding ability of a cyclodextrin. This effect is attributable to the increase in the apolar nature of the cavity due to the capping by the apolar groups. For example, capped )8-cyclodextrin (la) binds sodium l-anilino-8-naphthalenesulfonate 24 times better than parent -cyclodextrin [5]. The binding ability of another capped j8-cyclodextrin (lb) changes on photoirradiation, since the conformation of /8-cyclodextrin is varied due to the cis-trans photoisomerization of the azobenzene moiety [6]. 

Further studies of the photochemically induced conversion of JV-methyl-diphenylamine into N-methylcarbazole have been reported.28 Two successive intermediates have been detected, namely the amine triplet and iV-methyl-4a,4b-dihydrocarbazole. Oxygen appears to participate in the overall reaction in two ways, viz. by dehydrogenation of the dihydrocarbazole intermediate to carbazole and by quenching the amine triplet. Non-oxidative cyclization of 5-(iV-methyl-anilino)- and 5-(iV-acetylanilino)-l,3-dimethyluracil (26) similarly gives the trans-dihydropyrimido[5,4-6]indoles (27) in high yield.24 Orbital symmetry arguments... 

Cl4H16CI6N6P4, 2-trans-4,6,6,8,8-Hexachloro-2,4-bis(N-methyl-anilino)eyelotetraphosphazatetraene, 43B, 861 Cl4H16Cl6NeP4, 2,4,4,trans-6,8,8-Hexachloro-2,6-bis(N-methyl-anilino)cyclotetraphosphazatetraene, 43B, 860 Cl4H16P4N2P2r Diazadiphosphetidin, 41B, 736 Cl4H1sNOP, N,N-Dimethyldiphenylphosphinamide, 42B, 542... 

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