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And insertion

At this point an interesting simplification can be made if it is assumed that r, as representing the depth in which the ion discrimination occurs, is taken to be just equal to 1/x, the ion atmosphere thickness given by Debye-Hiickel theory (see Section V-2). In the present case of a 1 1 electrolyte, k = (8ire V/1000eitr) / c /, and on making the substitution into Eq. XV-7 and inserting numbers (for the case of water at 20°C), one obtains, for t/ o in millivolts ... [Pg.554]

Filling and sealing the Carius tube. Introduce 100-150 mg. of powdered silver nitrate into the Carius tube, either through a spill of filter -paper rolled and inserted as described on p.418, or through a small funnel, so that the powder falls freely to the bottom of the tube and does not touch or adhere to the walls. [Pg.503]

After the assembly and insertion of the boundai conditions the following set of global stiffness equations is derived... [Pg.57]

Now, calculating all //y and 5y elements in the same way, and inserting them into the seeular matiix, one obtains... [Pg.234]

Cholestenone. Place a mixture of 1 0 g. of purified cholesterol and 0-2 g. of cupric oxide in a test-tube clamped securely at the top, add a fragment of Dry Ice in order to displace the air by carbon dioxide, and insert a plug of cotton wool in the mouth of the tube. Heat in a metal bath at 300-315° for 15 minutes and allow to cool rotate the test-tube occasionally in order to spread the melt on the sides. Warm with a few ml. of benzene and pour the black suspension directly into the top of a previously prepared chromatographic column (1) rinse the test-tube with a little more benzene and pour the rinsings into the column. With the aid of shght suction (> 3-4 cm. of mercury), draw the solution into the alumina column stir the top 0 -5 cm. or so with a stout copper wire to... [Pg.944]

Reaction of free-base porphyrin compounds with iton(II) salts in an appropriate solvent results in loss of the two N—H protons and insertion of iron into the tetradentate porphyrin dianion ligand. Five-coordinate iton(III) porphyrin complexes (hemins), which usually have the anion of the iton(II) salt for the fifth or axial ligand, ate isolated if the reaction is carried out in the presence of air. Iron(II) porphyrin complexes (hemes) can be isolated if the reaction and workup is conducted under rigorously anaerobic conditions. Typically, however, iton(II) complexes are obtained from iton(III) porphyrin complexes by reduction with dithionite, thiolate, borohydtide, chromous ion, or other reducing agents. [Pg.441]

The Model 412 PWR uses several control mechanisms. The first is the control cluster, consisting of a set of 25 hafnium metal rods coimected by a spider and inserted in the vacant spaces of 53 of the fuel assembhes (see Fig. 6). The clusters can be moved up and down, or released to shut down the reactor quickly. The rods are also used to (/) provide positive reactivity for the startup of the reactor from cold conditions, (2) make adjustments in power that fit the load demand on the system, (J) help shape the core power distribution to assure favorable fuel consumption and avoid hot spots on fuel cladding, and (4) compensate for the production and consumption of the strongly neutron-absorbing fission product xenon-135. Other PWRs use an alloy of cadmium, indium, and silver, all strong neutron absorbers, as control material. [Pg.217]


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See also in sourсe #XX -- [ Pg.251 ]




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Addition and insertion reactions of methylene

Alkene and Alkyne Insertion

Alkene and Alkyne Insertion Reactions

Alkene, Alkyne, and Carbene Insertion

And carbene insertion

Biosynthesis and insertion into the membrane

Carbene Additions and Insertions

Carbenes and carbenoid intermediates insertion reactions

Carbonylation and other migratory insertion reactions

Cyclopropanation and C-H Insertion

Cyclopropanations and C-H Insertion Reactions

Dihalo- and monohalocarbene complexes migratory insertion reactions

Dirhodium(ll) Carboxamidates for Asymmetric Cyclopropanation and Carbon-Hydrogen Insertion Reactions

Elimination and 1.1-insertion involving alkylidene ligands

Elimination and insertion reactions

From an Isocyanide via Insertion and Rearrangement

Galvanized Inserts and Molds

Insertion Reactions of Carbon Monoxide and Isonitriles

Insertion Reactions of Transition Metal-Carbon cr-Bonded Compounds. II. Sulfur Dioxide and Other Molecules

Insertion and Deinsertion

Insertion and Isomerization Reactions

Insertion and elimination

Insertion and migration

Insertion into main group and post-transition metal amides

Insertion of Alkenes and Alkynes

Insertion of alkyne and

Insertion, Abstraction, and Rearrangement Reactions of Carbenes

Insertions and deletions

Kinetics and Mechanism of Carbon Monoxide Insertion

Kinetics and Mechanism of Sulfur Dioxide Insertion

Ligation of pHEN-1 and insert antibody scFv

Migratory Insertion and Elimination

Monoxide Insertion. General Considerations and Background

Oxidative addition and insertion

Proton Insertion in Polycrystalline WO3 Studied with Electron Spectroscopy and Semi-empirical Calculations

Reactions of Internal and Terminal Alkynes via Insertion

Reactions via Insertion of Alkenes and Alkynes

Reverse reactions, for CO migration and alkyl insertion

Sulfur Dioxide Insertion. General Considerations and Background

Syndiospecific Transition State Structure and Syndio-Insertion Catalytic Cycle

Theoretical studies and basic features of the insertion step

Transcription and Translation of Plasmid Inserts by their Hosts

Transposons and Insertion Sequences

Yuzo Fujiwara and Chengguo Jia 2 Palladium-Catalyzed Carbonylative Oxidation Other than Those Involving Migratory Insertion

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