3-Amino-3-aminomethyl-2- -2-methyl

LI[A1H4]/THF Riickfl.. 18 h 2-Aminomethyl-1,3-di-amino-2-methyl-propan 85 3... [Pg.970]

Amino-5-aminomethyl-3-benzyltriazole and S-methylisothiuronium acetate, refluxed in ethanol, gave the acetate of 4-amino-3-benzyl-5-(guanidinomethyl)triazole (38) (1 hr, 75%) [80JCS(P1)2918], 4-Amino-3-benzyl-5-(trifluoroacetamidomethyl) triazole, when stirred with iodomethane and potassium carbonate in dimethylformamide, afforded 4-amino-3-methyl-5-(fV-methyltrifluoroacetamidomethyl)triazole (24°C, 1.5 hr, 74%) [78JCS(P1)513]. [Pg.162]

Amino-2 -methoxydiphenyl, 336 Aminomethylation, 420 2-Amino-2-methylbutyric add, 274 2-Amino-2-methyl-l-propanol, 540 Aminopyrazoles, 137 Aminopyrimidines, 137 2-Aminoquinolines, 396 2-Amino-l, 4-quinones, 58 30-Amino steroids, 288 2-Aminothiazole, 19... [Pg.316]

Aminomethyl- 197 2-Amino-3-mcthyl- 336 2-Amino-4-methyl- 5, 49, 94, 223, 352 2-Amino-5-methyl- 28, 84... [Pg.1136]

Aminomethyl-2-mercapto- 197 2-Amino-4-methyl-5-nitro- 21, 166 2-Amino-5-methyl-4-(3-nitro-phenyl)- 64 2-Amino-4-methyl-5-(4-nitro-phenylthio)- 293... [Pg.1136]

Amino-4-methylamino- 538 3-Amino-2-methyl-4,5-bis-[aminomethyl]- 125 3-Amino-2-oxo-1-methyl-1,2-dihydro- 77 (Amino-phenoxy)- 535... [Pg.854]

Amino-5-hydroxy-2,3-diphenyl- 539 2-Amino-5-methyl-3-aminomethyl- 143 2-Amino-4-methyl-3-cyan- 143 2-Anilinocarbonyl- 324 2-Anilinocarbonyl- 3,4,5.6-tetrahydro-... [Pg.857]

Beilstein Handbook Reference) A13-03949 Aminoglycol Aminomethyl propanediol 2-Amino-2-methyl-1,3-propandiol 2-Amino-2-methyl-propanediol 2-Amino-2-methylpropane-1,3-dlol AMPD BRN 0635708 1,1-... [Pg.28]

A similar reaction was accomplished with cyanogen bromide. When the appropriate N-alkyl-4-amino-5-aminomethyl-1,2,3-triazoles were refluxed with cyanogen bromide in methanol, 2-amino-1-methyl-, 2-methyl-, and 3-benzyltriazoles were obtained in 40-75% yields.66... [Pg.21]

Similar attempts to cyclize 4-amino-3-benzyl- or 4-amino-1-methy 1-5-ethoxalylaminomethyl-1,2,3-triazole (see 20) were unsuccessful. Surprisingly, 5-aminomethyl-3-benzyl- and 5-aminomethy 1-1 -methy 1-4-oxamoylamino-1,2,3-triazoles spontaneously isomerized to 4-amino-3-benzyl- and 4-amino-l-methyl-5-oxamoylaminomethyl-l,2,3-triazoles, which resisted ring closure with stannic chloride, phosphoryl chloride, or boiling butanolic sodium butoxide.69... [Pg.23]

Ohba and co-workers developed a general synthesis of chiral iV-protected 5-(aminomethyl)oxazoles from a-lithiated isocyanides and Af-protected amino acid esters (Scheme 1.101). Metalation of an alkyl or benzyl isocyanide with n-BuLi or LDA and acylation with an A-Boc-ot-amino acid methyl ester afforded an iV-Boc-a-amino acid acyl isocyanide 369, which cyclized to a chiral A-Boc-5-(aminomethyl) oxazole 370. The products were obtained in > 98% ee based on chiral HPLC analysis. The yields of 370 were somewhat variable, ranging from 45 to 91%. A-Boc-protected glycine, alanine, phenylalanine, proline, serine, and (9-benzyl serine were all compatible with these reaction conditions. [Pg.80]

Amino-2-methyl-1,3-propanediol. See Aminomethyl propanediol Aminomethyl propanol CAS 124-68-5 EINECS/ELINCS 204-709-8 Synonyms 2-Amino-2,2-dimethylethanol 2-Amino-2-methyl-1-propanol AMP 1,1-Dimethyl-2-hydroxyethylamine Isobutanolamine... [Pg.230]

See AMP isostearoyl hydrolyzed collagen AMP isostearoyl hydrolyzed collagen CAS 95032-84-1 222400-36-4 Synonyms AMP-isostearoyl hydrolyzed animal protein Collagen, hydrolysates, isostearoyl, compds. with 2-amino-2-methyl-1-propanol Definition Aminomethyl propanol salt of isostearoyl hydrolyzed collagen... [Pg.288]

Cnlor-l-amino-heptsn 4,194. 6-Chlor-2-amino.3-methyl-hexan 4,196. C-Chloi-y.aminomethyl-hezan 4,195. Dimethyl. [a-methyl.allyl]>aiiun.ehlor>... [Pg.190]

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