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Amine electron transfer bridge

Busch and Pennington have prepared the [Co OP(02H)CH(Me)NH3 (NH3)5] + ion containing O-bound 1-aminoethylphosphoric acid, but it remains to be isolated and fully characterized. The terminal amine group has a of 3.2 and the deprotonated complex acts as a bridge for intersphere electron transfer with Cr qj. A scries of diphosphonate chelates of type (164) have been prepared (Table 47) and fully characterized. Crystal structures on the parent (R, = H) bis(ethylenedi-... [Pg.766]

Photolysis " of the ion pair (NH3)RuCf -Ru(CN)r leads to reduction of the amine complex which rapidly hydrolyzes. A further inner-sphere electron transfer gives the bridged product [(NH3)5Ru(III)NCRu(II)-(CN)5]. [Pg.49]

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See also in sourсe #XX -- [ Pg.566 ]



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