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Allylic Amines and Ethers

2 Substrates and Metallation Conditions 2.1 Allylic Amines and Ethers [Pg.105]

BuLi t-BuOK, THF-hexane BuLi TMEDA, hexane [Pg.106]

THF-hexane KNH2, liq.,NH3 BuLi, THF-hexane (5) KNH2, liq. NH3(10) [Pg.106]

THF-hexane, HMPT BuLi, Et20-hexane (10) [Pg.106]

Whereas in the cases of metallated allylic amines and ethers the products resulting from y-attack are predominantly Z-isomers, the y-products obtained from reactions with metallated allyl trimethylsilane are exclusively E-isomers. [Pg.117]

See other pages where Allylic Amines and Ethers is mentioned: [Pg.118] [Pg.974]

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Allyl amine

Allyl ethers

Allylic amination

Allylic aminations

Amine ether

Amines allylation

Rhodium-Catalyzed Nucleophilic Ring Cleaving Reactions of Allylic Ethers and Amines