Alkyl photolysis

ESR spectra, 7, 19 Diaziridinyl radicals ESR, 7, 202 reactions, 7, 19 Diazirine, alkyl-photolysis, 7, 225-226 synthesis... 

Because di-/ fZ-alkyl peroxides are less susceptible to radical-induced decompositions, they are safer and more efficient radical generators than primary or secondary dialkyl peroxides. They are the preferred dialkyl peroxides for generating free radicals for commercial appHcations. Without reactive substrates present, di-/ fZ-alkyl peroxides decompose to generate alcohols, ketones, hydrocarbons, and minor amounts of ethers, epoxides, and carbon monoxide. Photolysis of di-/ fZ-butyl peroxide generates / fZ-butoxy radicals at low temperatures (75), whereas thermolysis at high temperatures generates methyl radicals by P-scission (44). 

Photolysis of pyridazine IV-oxide and alkylated pyridazine IV-oxides results in deoxygenation. When this is carried out in the presence of aromatic or methylated aromatic solvents or cyclohexane, the corresponding phenols, hydroxymethyl derivatives or cyclohexanol are formed in addition to pyridazines. In the presence of cyclohexene, cyclohexene oxide and cyclohexanone are generated. 

Isoxazolin-5-one, 2,3-dimethyl-4-substituted photolysis, 6, 14 Isoxazolinones synthesis, 5, 132 Isoxazolin-3-ones alkylation, 6, 43 synthesis, 6, 106, 129 Isoxazolin-4-ones synthesis, 6, 106-107 Isoxazolin-5-ones alkylation, 6, 39 4,4-dialkyl substituted... 

Oxetane, 2-(o -chlorobenzyl)-2-phenyl-X-ray crystal structure, 7, 366 Oxetane, 3-chloromethyl-3-ethyl-ring strain, 7, 370-371 Oxetane, 2-(o-chlorophenyl)- H NMR, 7, 367 Oxetane, 2-cyano-synthesis, 7, 391-392 Oxetane, 2-cyano-3,3-dimethyl-2-phenyl-thermolysis, 7, 372 Oxetane, 2,2-dialkoxy-synthesis, 7, 396 Oxetane, 2,2-dialkyl-isomerization, 7, 377 Oxetane, 3,3-dialkyl-alkylative cleavage, 7, 381 polymers, 7, 382 Oxetane, 2-diethylamino-synthesis, 7, 390 Oxetane, 3,3-difluoro-molecular dimensions, 7, 365 Oxetane, 2,2-dimethyl-mass spectra, 7, 368-369 photolysis, 7, 373 synthesis, 7, 393 Oxetane, 2,3-dimethyl- H NMR, 7, 366 thermolysis, 7, 372 Oxetane, 2,4-dimethyl-mass spectrum, 7, 369... 

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