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Alkene sulfone alkyl aryl

Fragmentation Loss of alkyl by fragmentation of the C-O bond with concomitant double H rearrangement to form the protonated sulfonic acid ion (m/z 97 for methanesulfonates), which then loses water. Loss of the alkoxyl residue (fragmentation of the S-O bond). Formation of an alkene ion from the sulfonate alkyl by a McLafferty-type rearrangement. In aryl esters, the phenoxy ion and the phenol radical cations dominate the spectrum. [Pg.425]

Trialkylboranes react rapidly and in high yields with a-halo ketones,a-halo esters, a-halo nitriles, and a-halo sulfonyl derivatives (sulfones, sulfonic esters, sulfonamides) in the presence of a base to give, respectively, alkylated ketones, esters, nitriles, and sulfonyl derivatives. Potassium tert-butoxide is often a suitable base, but potassium 2,6-di-tert-butylphenoxide at 0°C in THF gives better results in most cases, possibly because the large bulk of the two tert-buXy groups prevents the base from coordinating with the R3B. The trialkylboranes are prepared by treatment of 3 mol of an alkene with 1 mol of BH3 (15-16). With appropriate boranes, the R group transferred to a-halo ketones, nitriles, and esters can be vinylic, or (for a-halo ketones and esters) aryl. " °... [Pg.560]

Organoboranes react with a mixture of aqueous NH3 and NaOCl to produce primary amines. It is likely that the actual reagent is chloramine NH2CI. Chloramine itself,hydroxylamine-O-sulfonic acid in diglyme, and trimethyl-silyl azide " also give the reaction. Since the boranes can be prepared by the hydroboration of alkenes (15-16), this is an indirect method for the addition of NH3 to a double bond with anti-Markovnikov orientation. Secondary amines can be prepared by the treatment of alkyl- or aryldichloroboranes or dialkylchlorobor-anes with alkyl or aryl azides. [Pg.800]

Hydrozirconation of terminal alkynes R-C=CH (R= aryl, alkyl) with 1 affords terminally ( )-Zr-substituted alkenes with high efficiency and excellent stereochemical and regiochemical control (>98%). These alkenylzirconocene complexes are of particular interest for synthetic use [136, 143, 144]. Moreover, beside the electropositive halogen sources [145] and heteroatom electrophiles [3] used in the pioneering studies to directly cleave the Zr-C bond, ( )-vinyl-Zr complexes were recently transformed into a number of other trans-functionalized alkenes such as ( )-vinyl-sul-fides[146], vinylic selenol esters [147], vinyl-sulfones [148], vinyl-iodonium [149], vinyl-(R0)2P(0) [150], and vinilic tellurides [143]. [Pg.264]

Another general process involves the reaction of Pd(0) species with halides or sulfonates by oxidative addition, generating reactive intermediates having the organic group attached to Pd(II) by a ct bond. The oxidative addition reaction is very useful for aryl and alkenyl halides, but the products from saturated alkyl halides often decompose by (3-elimination. The a-bonded species formed by oxidative addition can react with alkenes and other unsaturated compounds to form new carbon-carbon bonds. The... [Pg.707]

The Heck reaction is a C-C coupling reaction where an unsaturated hydrocarbon or arene halide/triflate/sulfonate reacts with an alkene in presence of a base and Pd(0) catalyst so as to form a substituted alkene. Kaufmann et al. showed that the Heck reaction carried out in presence of ILs such as tetra-alkyl ammonium and phosphonium salts without the phosphine ligands, resulted in high yields of product. They attributed the activity to the stabilizing effect of ammonium and phosphonium salts on Pd(0) species. Carmichael et al. used ionic liquids containing either A,A -dialkylimidazolium and A-alkylpyridinium cations with anions such as halide, hexafluorophosphate or tetrafiuoroborate to carry out reactions of aryl halide and benzoic anhydride with ethyl and butyl acrylates in presence of Pd catalyst. An example of iodobenzene reacting with ethyl acrylate to give trans-et vy cinnamate is shown in Scheme 14. [Pg.168]


See other pages where Alkene sulfone alkyl aryl is mentioned: [Pg.2098]    [Pg.2428]    [Pg.2534]    [Pg.2548]    [Pg.2098]    [Pg.2183]    [Pg.2428]    [Pg.2534]    [Pg.2548]    [Pg.1071]    [Pg.1236]    [Pg.1296]    [Pg.2098]    [Pg.2428]    [Pg.2534]    [Pg.2548]    [Pg.2098]    [Pg.2183]    [Pg.2428]    [Pg.2534]    [Pg.2548]    [Pg.1071]    [Pg.1236]    [Pg.1296]    [Pg.2111]    [Pg.2113]    [Pg.2546]    [Pg.2111]    [Pg.2113]    [Pg.2546]    [Pg.1043]    [Pg.2378]    [Pg.2379]    [Pg.2472]    [Pg.2581]    [Pg.137]    [Pg.137]    [Pg.476]    [Pg.375]    [Pg.543]    [Pg.24]    [Pg.500]    [Pg.65]    [Pg.458]    [Pg.617]   
See also in sourсe #XX -- [ Pg.281 , Pg.283 , Pg.284 , Pg.336 , Pg.347 , Pg.562 ]




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Alkene sulfonates

Alkenes alkyl sulfonates

Alkenes alkylated

Alkyl Aryl Sulfones

Alkyl aryl sulfonates

Alkyl aryl sulfone

Alkyl sulfonate

Alkylation alkene

Alkylation sulfonates

Aryl sulfone

Sulfone alkylation

Sulfones alkylation

Sulfones, alkyl

Sulfones, alkyl alkylation

Sulfones, aryl

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