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Alkali metal magnesiates lithium

Magnesium amides can form a wide range of mixed metal amido complexes with alkali metal ions (M2[Mg(NH2)4]) (M = K, Rb or Cs).These contain tetrahedral Mg-centered [Mg(NH2)4] ions connected in three-dimensional networks by coordination of the amido groups to the group 1 metal ions. The most common hetero metal is lithium and lithium amido magnesiates are readily accessible by the addition of a lithium amide to a magnesium amide. [Pg.52]

Garcia-AlvarezJ, Graham DV, Hevia E, Kennedy AR, Mulvey RE. Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetyhdes structural variations in bimetallic lithium- and sodium-heteroleptic magnesiates. Dalton Trans. 2008 (11) 1481—1486. [Pg.45]

See other pages where Alkali metal magnesiates lithium is mentioned: [Pg.117]    [Pg.137]    [Pg.194]    [Pg.2]    [Pg.116]    [Pg.118]    [Pg.121]    [Pg.26]    [Pg.154]   


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