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These trihydroxy sulfoxides are useful molecules in total synthesis because of the possible transformation of the sulfoxide into aldehyde by a Pummerer rearrangement. Homoallylic 3-hydroxy sulfoxides have also been prepared from 3-epoxy sulfoxides, readily obtained from methyl monochloroacetate (Scheme 61a). ... [Pg.156]

See other pages where Aldehydes preparation from epoxy sulfoxides is mentioned: [Pg.744]

See also in sourсe #XX -- [ Pg.417 ]

See also in sourсe #XX -- [ Pg.417 ]

See also in sourсe #XX -- [ Pg.417 ]