Albright-Onodera oxidation

Albright-Onodera Oxidation (Phosphorous Pentoxide-Mediated Moffatt Oxidation)... [Pg.118]

The Albright-Onodera oxidation is seldom used in organic synthesis and, therefore, no extensive experimental database is available that would provide information on its scope and limitations. Nonetheless, it must be mentioned that this oxidation tends to be used as a last resort when more common oxidation protocols fail, and in such cases, very often, it proves to be superior than other common oxidants. The Albright-Onodera oxidation is very conveniently carried out at room temperature using very cheap reagents, and resulting in water soluble side compounds that greatly simplify the work-up. [Pg.119]

General Procedure of Albright-Onodera Oxidation Using Taber Modification... [Pg.119]

Treatment of the starting alcohol under Swern conditions gave chlorinated products, while chromic acid gave a low yield, and PCC led to a complex separation of the product from chromium-containing residues. An excellent yield of the desired ketone was obtained by using the Taber modification of the Albright-Onodera oxidation. [Pg.120]

Functional Group and Protecting Group Sensitivity to Albright-Onodera Oxidation... [Pg.120]

It is known that acetals,78 (3-lactams,79 TBS ethers76 and alkenes75 resist the action of the Albright-Onodera oxidation. [Pg.120]

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...