Adsorption heat effects during

Among the external processes possibly influencing the rate of overall adsorption, the access of the dif-fusants into the sorption vessel and the dissipation of the adsorption heat deserve special attention. A substantial number of models have been developed to quantify these influences, which are generally referred to as the valve effect [37-39] and the heat effect [2, 40-42], In turn, in Ref. 43 a novel method for uptake measurements has been based on the heat effect during molecular sorption. By IR monitoring of the surface temperature it has become possible to acquire a second, independent source of information about the internal processes within the sample, yielding useful in formation in particular for fast processes. 

The adsorption column should be supplied with a number of thermocouples to observe heat effects during sorption. Also a supply system for sorptive gases and a carrier gas (He, Ar, N2) should be provided including well calibrated flow meters to set up mass balances. 

Alternatively, peak asymmetry could arise from thermal effects. During the passage of a solute along the column the heats of adsorption and desorption that are evolved and adsorbed as the solute distributes itself between the phases. At the front of the peak, where the solute is being continually adsorbed, the heat of adsorption will be evolved and thus the front of the peak will be at a temperature above its surroundings. Conversely, at the rear of the peak, where there will be a net desorption of solute, heat will be adsorbed and the temperature or the rear of the peak will fall below its surroundings. 

Thermogravimetry can be used to measure the amount of water [232] or other molecule adsorbed on a zeolite. DSC can be uhlized to study the thermal effects during adsorption and desorphon of water [233] because the peak area under the heat flow time curve is related to the sorption heat. 

After the adsorption of oxygen, the sample is replaced under vacuum at 30°C. No desorption occurs, and no thermal effect is registered. Carbon monoxide may be adsorbed again, and its adsorption is followed by a decrease of the electrical conductivity of the sample from 1.6 X 10"7 to 1.6 X 10 10 (ohm cm.)-1. The differential heats measured during the... 

The heat of adsorption of the cesium ion, Q however, does not remain constant, but increases during further adsorption. This effect is... 

The enthalpies of adsorption as already defined are adequate for an experiment when a clean adsorbent is immersed in the solution, but they are not suited for other experiments, which are usually more accurate where the adsorbent is initially immersed in the pure solvent. When the pure solvent is replaced by a solution of molality b2, adsorption of the solute can only take place by displacement of the solvent. The word displacement is used here to indicate that the adsorption of the amount nfn) of solute produces the desorption of a corresponding (but usually not equal) amount of solvent. Following Kiraly and Dekany (1989), let us call r the amount of solvent displaced (i.e. desorbed) by one mole of solute, therefore producing a change in composition of the solution and giving an enthalpy of mixing, A mixH, which is part of the overall heat effect, Qnp, measured during the experiment. It is preferable not to include A mixH (which is not a property of the interface) in the definition of the enthalpy of displacement, which is therefore ... 

Thermometric sensors are based on the measurement of the heat effects of a specific chemical reaction or an adsorption process that involves the analyte. In this group of sensors the heat effects may be measured in various ways, for example in catalytic sensors the heat of a combustion reaction or an enzymatic reaction is measured by use of a thermistor. Calorimetric biosensors detect variations of heat during a biological reaction. 

The conclusion so far must be that synthesis and sample preparation techniques play an important role. Diffusion data to be used in permeation experiments should be measured on membranes with techniques which reflect as closely as possible the transport phenomena during permeation. This also minimises heat effects due to adsorption/desorption which play an important role in diffusion experiments based on large crystals, but is of minor importance in membrane experiments [101]. 

In the last section we have illustrated the essential behaviors of isothermal single component systems. In this section we will address the effect of heat release during the adsorption step or heat absorption during the desorption step on the adsorption kinetics. What we need is simply an extra equation to account for the heat balance around the particle. To make the analysis more general, we shall take adsorption isotherm being arbitrary. 

In a number of instances adsorption of polar compounds from dilute solutions passes through a region in which the surface is covered by a closely packed monolayer of the polar solute. The author discovered in 1966 that most non-porous metal oxides adsorb preferentially n-butanol from n-heptane with the formation of such a monolayer. The integral heat produced during the formation of the monolayer correlated very well with the specific areas of the metal oxides measured by the BET(Na) method [26], The specific surface areas of these solids could be effectively measured by a single point method, in which a sample of the solid immersed in n-heptane was flooded with a 2 gl > solution of n-butanol producing a heat of n-heptane displacement which was proportional to the total surface area of the sample. 

The operating environmental temperature has an effect on the carbon canister performance [20]. Fig. 14 shows a 10% degradation in GWC as the environmental temperature increases from 25 to 80 °C. The hydrocarbon heel decreases by 55% during the same test. The hot environment helps to pui ge out the canister, but adsorption is reduced under the same conditions. Ideally the canister would be packaged in an area where it would not pick up heat from vehicle operation. 

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