Adsorption-desorption kinetics in batch rebinding experiments

Adsorption-desorption kinetics in batch rebinding experiments 

As follows from the equilibrium expression for the association of two molecules [38], 

Peak dispersion and asymmetry in chromatography using MlP-phases 

Since the retention of the template on the imprinted polymers strongly depends on the sample load (see later Fig. 5.25), the theoretical models describing the various dispersion processes are not applicable. Nevertheless, on an imprinted CSP for L-PA, the least retained enantiomer, D-PA, elutes as a fairly Gaussian peak (Fig. 5.3), which should be governed by the same band broadening mechanisms that are considered in the models. A measure of the dispersion of a Gaussian peak is the deviation from its mean value, which is reflected in the reduced plate height as  

For porous ion exchange resins it has been found that h depends on u approximately as  

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