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Additives/cosolvents proton sources

Additives (cosolvents) which serve as ligands have great influence on the reducing power of Smlj. Allylic and propargylic derivatives are reduced via it-allylpalladium species, and the proton source has important effects on the generation of allenes or alkynes. Chiral allenic esters are obtained when pantolactone delivers a proton to racemic organosamarium species derived from 4-phosphato-2-alkynoic esters. ... [Pg.327]

See other pages where Additives/cosolvents proton sources is mentioned: [Pg.82]    [Pg.376]    [Pg.378]    [Pg.670]    [Pg.1004]    [Pg.398]    [Pg.751]    [Pg.164]   
See also in sourсe #XX -- [ Pg.12 , Pg.13 , Pg.14 ]



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Additives/cosolvents

Cosolvents

Proton addition

Proton source

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