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Adamantane like cage

Fig. 10. The structure of [(CH3)2Ge]6P4, emphasizing the adamantane-like cage arrangement of germanium and phosphorus atoms. Fig. 10. The structure of [(CH3)2Ge]6P4, emphasizing the adamantane-like cage arrangement of germanium and phosphorus atoms.
Tellurium coordination is seen in a series of acychc bidentate ligands that coordinate through Te N donor atoms or Te donor atoms An interesting series of adamantane-like cage complex cations that contain mercury(II) have been prepared and have the general formula [ j,-ER2(HgL)4] + (E = S, Se,orTe L = phosphine or arsine). These cations contain a variety of Hg-L bonds and have been characterized using heteronuclear NMR ( P, Te, Hg). [Pg.2595]

Several chalcogen-bridged clusters of the group 12 metals (Zn, Cd, Hg) have been synthesized utilizing silylated reagents. Mostly, the structures of these complexes are based on adamantane-like cages, and are similar to II-VI clusters synthesized by other approaches, as described in... [Pg.94]

The pyrolysis of bis[bis(trimethylsilyl)arsino]dimethylsilane leads to the adamantane-like cage [(H3C)2Si]eAs4 [423]. The cage [(HgQjSijgP can be obtained by pyrolysis of bis(phosphino)dimethylsilane (Eq. 3.223) ... [Pg.87]

See other pages where Adamantane like cage is mentioned: [Pg.29]    [Pg.294]    [Pg.733]    [Pg.733]    [Pg.101]    [Pg.575]    [Pg.1887]    [Pg.272]    [Pg.175]    [Pg.358]    [Pg.367]    [Pg.537]    [Pg.2672]    [Pg.2676]    [Pg.29]    [Pg.367]    [Pg.459]    [Pg.483]    [Pg.843]    [Pg.2671]    [Pg.2675]    [Pg.5448]    [Pg.227]    [Pg.78]    [Pg.113]    [Pg.124]    [Pg.1887]    [Pg.173]   
See also in sourсe #XX -- [ Pg.173 , Pg.174 ]



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