Acyclic Dienes as Cyclization Precursors

For recent reviews of the asymmetric Heck reaction, see (a) Shibasaki, M., Boden, C.D.J. and Kojima, A. (1997) The asymmetric Heck reaction. Tetrahedron, 53, 7371-95 (b) Shibasaki, M. and Vogl, E.M. (1999) Heck reaction, in Comprehensive Asymmetric Catalysis, Vol. 2 (eds E.N. Jacobsen, A. Pfaltz and H. Yamamoto), Springer, Berlin, pp. 457-87 (c) Donde, Y. and Overman, L.E. (2000) Asymmetric intramolecular Heck reactions, in Catalytic Asymmetric Synthesis (ed. I. Ojima), WUey-VCH Verlag GmbH, New York, pp. 675-97 (d) Dounay, A.B. and Overman, L.E. (2003) The as5mmetric intramolecular Heck reaction in natural product total synthesis. Chem. Rev., 103, 2945-64 (e) Shibasaki, M., Vogl, E.M. and Ohshima, T. (2004) Asymmetric Heck reaction. Adv. Synth. Catal., 346,1533-52. 

For a representative review, see Kagan, H.B., Diter, R, Gref, A., et al. (1996) Towards new ferrocenyl ligands for asymmetric catalysis. PureAppl. Chem., 68, 29-36, and references cited therein. 

(1985) Palladium Reagents in Organic Synthesis, Academic Press, London. 

(1979) Palladium-catalyzed reactions of organic halides with olefins. Acc. Chem. Res., 12, 146-51. 

Sodeoka, M. and Shibasaki, M. (1989) Catalytic asymmetric C—C bond formation asymmetric synthesis of cw-decalin derivatives by palladium-catalyzed cyclization of prochiral alkenyl iodides. J. Org. Chem., 54, 4738-9. 

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