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Acutumine

Acutumine, C20(ai)H87OgN. This base, isolated by Goto and Sudzuki,... [Pg.272]

Menispermum dauricum L. Ye Dou Gen, Shan Dou Gen (Moonseed) (root) Dauricine, daurinoline, 1-stepharine, dauricoline, acutumine, tetrandrine, dauricinoline, stepholidine, magnoflorine, menisperine, sinomenine.33-505 Antiarrhythmic, analgesic effect, relieve headache, insomnia. [Pg.111]

China Menispermum dauricum L. Acutumine, acutuminine, dauricine, disinomenine, magnoflorine, menispermine, sinomenine, stepharine, tetrandrine.50 Antitumor, cytotoxic, alleviate skin allergies, antirheumatic, anticancer against esophageal cancer. [Pg.280]

N.A. Menispermum canadense L. Dauricine, tetrandrine, viburnito, acutumine, acutomidine, daurinoline, N-desmethyldauricine, magnoflorine.100 Fruits are toxic if eaten in quantity. Cyanogenetic, diuretic, laxative, nervine, stomachic. [Pg.280]

Scheme 10 Radical cyclization as key step in the total synthesis of acutumine (26) [75]... Scheme 10 Radical cyclization as key step in the total synthesis of acutumine (26) [75]...
In all the following examples, the targeted double bonds were activated by suitable substituents to increase the efficacy of the desired cyclization mode. For the total synthesis of acutumine (26), an activated a,p-unsaturated ketone 27 was chosen as precursor (Scheme 10) [74, 75], Aryl radical additions to this type of alkenes are known to proceed about ten times faster than to comparable allylic alcohols. In a radical-polar crossover reaction, the spirocyclic product 28 was obtained in the presence of triethylaluminum as promoter and an oxaziridine as hydroxylating agent. The fact that even the efficient hydrogen donor tetrahydrofuran could be used as solvent nicely demonstrates the high efficacy of the cyclization step. [Pg.40]

It is doubtful whether or not the acutumine, C20H27O8N, from Menispermum dahuricum DC. (257, 258), belongs to the group under discussion, but information to permit a definite relegation is not yet available. [Pg.122]

Sinoacutine and pallidine are found in Corydalis incisa (Pers.) (Fumariaceae)/ and the former alkaloid is also found in Stephania glabra (Menispermaceae). The chlorine-containing alkaloids acutumine and acutumidine are present in Menispermum canadense L. (Menispermaceae), and a full paper describing the isolation and structural elucidation of these two bases has been published. Hernandine (194) and hernandifoline (195) have been obtained from Stephania hernandifolia. [Pg.158]

Sinomenium acutum Rehder Sinactine (161), Tuduranine (162), Acutumine... [Pg.86]

See other pages where Acutumine is mentioned: [Pg.784]    [Pg.57]    [Pg.111]    [Pg.152]    [Pg.382]    [Pg.502]    [Pg.174]    [Pg.18]    [Pg.612]    [Pg.613]    [Pg.56]    [Pg.62]    [Pg.76]    [Pg.323]    [Pg.130]    [Pg.130]    [Pg.456]    [Pg.456]    [Pg.88]    [Pg.88]    [Pg.315]    [Pg.95]    [Pg.243]    [Pg.415]    [Pg.396]    [Pg.398]    [Pg.144]    [Pg.273]    [Pg.301]    [Pg.281]    [Pg.283]   
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See also in sourсe #XX -- [ Pg.40 ]

See also in sourсe #XX -- [ Pg.18 ]

See also in sourсe #XX -- [ Pg.456 ]

See also in sourсe #XX -- [ Pg.2 , Pg.220 ]

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See also in sourсe #XX -- [ Pg.160 ]

See also in sourсe #XX -- [ Pg.437 ]



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Acutumine alkaloids

The Castle Synthesis of (-)-Acutumine

Total synthesis acutumine

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