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Activators generated by electron transfer AGET

Poly(n-butyl acrylate) brushes were synthesized by activators generated by electron transfer (AGET) ATRP of BA from 2-bromoisobutyrate functionalized silica particles in miniemulsion imder conditions similar to those reported previously, BA Si02-Br CuBr2 BPMODA ascorbic acid = 600 1 0.5 0.5 ... [Pg.259]

SR NI evolved into activators generated by electron transfer (AGET) where an ATRP initiator is added to the reaction as a separate compound along with the higher oxidation state catalyst precursor for an active ATRP catalyst complex. The... [Pg.381]

Figure 20 Activator generated by electron transfer (AGET) ATRP. Activating species Cu Br/L is generated in situ by reduction of Cu"Br/L. Figure 20 Activator generated by electron transfer (AGET) ATRP. Activating species Cu Br/L is generated in situ by reduction of Cu"Br/L.
The next major step toward reducing the amount of catalyst needed to mediate polymerizations, which yield highly functionalized polymers, was the development another technique named activators generated by electron transfer AGET) The method is in some sense a logical continuation of... [Pg.338]

Better results again were obtained using a conventional ATRP initiation and in sHu catalyst (CuBri/BPMODA) reduction by AGET (Activator Generated by Electron Transfer)." In this case water soluble ascorbic acid was used as the reducing agent and it was presumed that catalyst reduction occurs in the aqueous phase. [Pg.498]

Scheme 24.2 Self-condensing vinyl polymerization [AGET (activators generated by electron transfer) ATRP] of 4-chloromethylstyrene. Scheme 24.2 Self-condensing vinyl polymerization [AGET (activators generated by electron transfer) ATRP] of 4-chloromethylstyrene.
See other pages where Activators generated by electron transfer AGET is mentioned: [Pg.213]    [Pg.309]    [Pg.27]    [Pg.131]    [Pg.219]    [Pg.303]    [Pg.464]    [Pg.163]    [Pg.13]    [Pg.18]    [Pg.43]    [Pg.484]    [Pg.75]    [Pg.95]    [Pg.213]    [Pg.309]    [Pg.27]    [Pg.131]    [Pg.219]    [Pg.303]    [Pg.464]    [Pg.163]    [Pg.13]    [Pg.18]    [Pg.43]    [Pg.484]    [Pg.75]    [Pg.95]    [Pg.287]    [Pg.80]    [Pg.20]    [Pg.126]    [Pg.214]    [Pg.50]    [Pg.36]    [Pg.217]    [Pg.3707]   
See also in sourсe #XX -- [ Pg.287 ]



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AGET (activators generated

Activation electronic

Activator generated by electron transfer

Activators generated by electron

By Electron Transfer

Electron activation

Electron generation

Electron transfer generation

Electrons active

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