Actinoids synthesis

Intermediate for the synthesis of actinoidic acid, degradation product of vancomycin... 

Intermediate for the 59 total synthesis of actinoidic acid derivatives... 

Our third example taken from a synthesis of the fully protected derivative 127,7 of Actinoidic Acid [Scheme 2.127], a constituent of Vancomycin, features the use of the oxazoline group as an activating group for an SNAr reaction, as a... 

Alkyl derivatives are more stable if the actinoid metal is also bound to cyclopentadienyl ligands and reactions 24.44-24.46 show general methods of synthesis where M = Th or U. 

Scheme 20 Synthesis of the actinoidic acid derivative 111 according to Uemura...

Cm are available on a 100 g scale, and multiple neutron capture followed by P -decay yields milligram amounts of Bk, Cf, Es and Es, plus microgram amounts of Fm. Synthesis of the heaviest actinoids was detailed in Section 3.6. Box 25.3 highlights an everyday use of "Am. 

In 2003, Danopoulos et al. successfully synthesized a CNC pincer ligand and used it to prepare a Pd complex. This ligand was later applied to the synthesis of ETM and actinoid complexes. Substitution of tmeda with the CNC pincer yielded [(NHC)VCl2(THF)] 37 (Equation (6.8)). This route was alternatively applied to the preparation of titanium, chromium, niobium and uranium complexes. ... 

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