Actinide complexes phthalocyanines

Acoustic emission diazine metal complexes, 80 Acrylonitrile metal complexes, 263 Actinide complexes cupferron, 510 dimethyl sulfoxide IR spectra, 490 phosphines SHAB theory, 1040 phthalocyanines, 864 thiocyanates, 236 Actins, 973 Acylates H3-ligands... 

More information on actinide phthalocyanine complexes is given in Sec. 5.1.6.2. 

Kadish, K. M., Moninot, G., Hu, Y., Dubois, D., Ibnlfassi, A., Barbe, J.-M., Guilard, R. (1993). Double-decker actinide porphyrins and phthalocyanines. Synthesis and spectroscopic characterization of neutral, oxidized, and reduced homo- and het-eroleptic complexes, J. Am. Chem. Soc., 115 8153. 

D.K.R Ng, J. Jiang, K. Kasuga and K. Machida conclude this volume with an overview of rare-earth and actinide half-sandwich tetrapyrrole complexes. When tetrapyrrole molecules, such as porphyrins or phthalocyanines, are reacted with the rare earths and actinides, they are split in half, forming the half-sandwich complexes because the metal atoms are larger than the core size of the macrocyclic ligands. They also can form sandwich-type complexes in which the metal centers are sandwiched between the macrocycles. However, this chapter is devoted to the former class of compounds. Ng and co-workers discuss the synthesis, structure, and spectroscopic and electrochemical properties of half-sandwich complexes of porphyrins and phthalocyanines. The authors... 

Phthalocyanine complexes of the sandwich type, in which the metal ion is held between two phthalocyanine macrocycles, can be built up on lanthanide and actinide matrices [485-487], For example, by interaction of MI4 (M = Th, U) with phthalonitrile at 240°C and subsequent extraction of the crude product with benzene and sublimation in vacuum, the products MPc2, where M = Th or U, were obtained [486]. 

Two specific metal-ligand systems merit mention because of the comprehensive research being carried out currently in the area of transition metal complexes metalloporphyrin derivatives of the lanthanide and actinide groups (Wong et al., 1974 Wong and Horrocks, 1975 Horrocks and Wong, 1976) and phthalocyanine derivatives of most of the rare earths prepared and characterized over the last 20 years (Kirin et al., 1965). 

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